White led lamp, backlight, light emitting device, display device and illumination device

ABSTRACT

A white LED lamp including: a conductive portion; a light emitting diode chip mounted on the conductive portion, for emitting a primary light having a peak wavelength of 360 nm to 420 nm; a transparent resin layer including a first hardened transparent resin, for sealing the light emitting diode chip; and a phosphor layer covering the transparent resin layer, the phosphor layer being formed by dispersing a phosphor powder into a second hardened transparent resin, and the phosphor powder receiving the primary light and radiating a secondary light having a wavelength longer than that of the primary light. An energy of the primary light contained in the radiated secondary light is 0.4 mW/lm or less. In the white LED lamp, a backlight, and an illumination device using the white LED lamp an amount of UV light to be contained in the released light and an amount of heat to be generated from the lamp are decreased to be small.

TECHNICAL FIELD

The present invention relates to a technical lighting device comprising:a light emitting diode for emitting UV light (ultraviolet light) topurple light as a primary light from the light emitting diode; and aphosphor layer for receiving the UV light to purple light and emitting awhite light; wherein the phosphor layer is composed of transparent resinand phosphor powder dispersed in the transparent resin, and the phosphorpowder receives the UV light to purple light and emits a secondary lighthaving a wavelength longer than that of the primary light. Moreparticularly, the present invention relates to a white LED (lightemitting diode) lamp, a backlight, a light emitting device, a displaydevice and an illumination device using the white LED lamp.

BACKGROUND ART

A light emitting diode (LED) is a semiconductor diode for radiatinglight, and has a function of converting an electrical energy intoultraviolet light or visible light.

Conventionally, there has been widely utilized a light emitting deviceusing an LED lamp. The LED lamp is manufactured, for example, in such amanner that a light emitting chip is formed by using a substrate such asa transparent substrate or the like and a light emitting material suchas GaP, GaAsP, GaAlAs, GaN, InGaN, AlGaN, InGaAlP or the like, then thelight emitting chip is sealed by a transparent resin.

When various phosphors are contained in a sealing resin, the LED lamp isable to adjust a color of the emitting light. That is, when a lightemitting chip for emitting a light and a phosphor powder for absorbingthe light and releasing a light having a predetermined range ofwavelength are combinatory used, it becomes possible to emit a light ora white light having a visible wavelength range, by the actions of thelight emitted from the light emitting chip and the light emitted fromthe phosphor powder.

As the white light emitting LED lamp for emitting the white light, awhite light emitting LED lamp using a blue light emitting diode chip anda white light emitting LED lamp using a UV light or a violet lightemitting diode chip are well known.

As the white light emitting LED lamp using a blue light emitting diodechip, there have been well known: an LED lamp in which a blue lightemitting diode chip and a red light emitting phosphor (red phosphor) anda green light emitting phosphor (green phosphor) or the like arecombined, (hereinafter referred to as “white LED lamp typel”); and anLED lamp using a blue light emitting diode chip and an yellow lightemitting phosphor (yellow phosphor) such as YAG or the like arecombined, (hereinafter referred to as “white LED lamp type 2”).

Furthermore, as the white light emitting LED lamp using a UV light orviolet light emitting diode chip, there has been well known an LED lampin which a UV light or violet light emitting diode chip and a redphosphor, a green phosphor and a blue phosphor or the like are combined,(hereinafter referred to as “white LED lamp type 3).

Because a color of the light emitted from the white LED lamp is white,the white LED lamp is used as a light source for a backlight of a liquidcrystal display device and a light source of an illumination device orthe like.

The white LED lamp used as the light source for the backlight of theliquid crystal display device is demanded to have various colorqualities such that a color reproducing property is wide, the lamp canbe designed to comprise a predetermined white chromaticity, a scatteringof the chromaticity is small, and the like.

Further, the white LED lamp used as the light source for theillumination device is demanded to have various color qualities suchthat a color rendering property is excellent, the lamp can be designedto comprise a predetermined white chromaticity, a color unevenness issmall, a scattering of the chromaticity is small, and the like.

Therefore, in a case where the white LED lamp is used as the lightsource for the backlight of the liquid crystal display device, the whiteLED lamps of type 1 and type 2 have raised the following problems.

Namely, the white LED lamp of type 1 has drawbacks such that the colorunevenness is large, the scattering of the chromaticity is also large,and the like. On the other hand, the white LED lamp of type 2 havedrawbacks such that the color reproducing property is narrow, the colorrendering property is not good, and the lamp can not be designed tocomprise a predetermined white chromaticity, and the like.

In contrast, according to the white LED lamp of type 3, it is possibleto satisfy the various color qualities such that the color reproducingproperty is broad, the lamp can be designed to comprise a predeterminedwhite chromaticity, the color rendering property is good, and the colorunevenness is small, and the like. Therefore, the white LED lamp of type3 is suitable as the light source for the backlight of the liquidcrystal display device and the light source of the illumination device.

For example, Japanese Patent Application (Unexamined Publication) No.2005-191420 (patent Document 1) discloses a white LED lamp of type 3.According to this white LED lamp, a luminous efficiency is increased tobe high.

On the other hand, in recent years, conventional Brown-tube televisionsas various display device have been replaced with thin-model televisionrepresented by a liquid crystal television or a plasma television. Theabove display device is disclosed in Japanese Patent Application(unexamined publication) No. 2000-49380 and Japanese Patent Application(unexamined publication) No. HEI 10-187062 (refer to Patent Documents 2and 3). The advantages and the disadvantages of the above displaydevices are collectively shown in Table 3.

As is clear from the results shown in Table 3, the advantages and thedisadvantages of the display devices vary in the respective technicalpoints. However, a main reason, why demand and market are shifting fromBrown-tube televisions to the thin-model televisions such as liquidcrystal television, plasma television or the like, has been confirmedthat the problem is a large depth, weight and size of the televisionrather than a problem of displayed image per se of the television.Accordingly, if the problem of the large size is solved while afavorable characteristic of Brown tube television is maintained as itis, it is said that an ideal display (display device) can be actuallyrealized.

-   Patent Document 1: Japanese Patent Application (Laid-Open) No.    2005-191420.-   Patent Document 2: Japanese Patent Application (Laid-Open) No.    2000-49380.-   Patent Document 3: Japanese Patent Application (Laid-Open) No. HEI    10-187062

DISCLOSURE OF INVENTION

However, according to the conventional white LED lamp of Type 3, when apart of UV light emitted from the light emitting diode chip is notconverted into a visible light and the non-converted UV light isreleased to outside the LED lamp, an affect of UV light and an affect ofheat generated from the white LED lamp act to each other whereby therehas been posed problems of causing the following phenomena.

Namely, in a case where the white LED lamp of Type 3 is used as a lightsource of backlight for a liquid display device, there arises problemssuch that resin-made peripheral members such as a light guide plate oroptical film or the like of the crystal liquid display device arechanged into yellow (yellow discoloration) whereby the luminance of thecrystal liquid display device is disadvantageously lowered, and anabnormal chromaticity occurs.

Further, in a case where the white LED lamp of Type 3 is used as a lightsource of an illumination device, there arises problems such that theilluminated object is damaged and a discoloration would occurs.Therefore, the conventional white LED lamp of Type 3 cannot be used as alight source of the illumination device provided to a picture galleryand art museum.

The white LED lamp of the present invention has been achieved to solvethe above conventional problems, and an object of the present inventionis to provide a white LED lamp in which an amount of UV light to becontained in the released light and an amount of heat to be generatedfrom the lamp are decreased to be small, and to provide a backlight andan illumination device using the white LED lamp.

The white LED lamp of the present invention capable of solving the aboveproblems is configured by comprising:

a conductive portion;

a light emitting diode chip, which is mounted on the conductive portion,for emitting a primary light having a peak wavelength of 360 nm to 420nm;

a transparent resin layer, which is composed of a first hardenedtransparent resin, for sealing the light emitting diode chip; and

a phosphor layer for covering the transparent resin layer, the phosphorlayer being formed by dispersing a phosphor powder into a secondhardened transparent resin, and the phosphor powder receiving theprimary light and radiating a secondary light having a wavelength longerthan that of the primary light,

wherein an energy of the primary light contained in the radiatedsecondary light is 0.4 mW/lm or less.

A backlight according to the present invention is capable of solving theabove problems, and is characterized by using the above white LED lamp.

An illumination device according to the present invention is capable ofsolving the above problems, and is characterized by using the abovewhite LED lamp.

In another aspect of the present invention, there is provided a lightemitting device comprising: a laser diode for emitting a laser lighthaving a peak wave length of 360 nm to 420 nm; and a phosphor layer forbeing excited by the laser light and emitting blue, green and redlights.

Further, a display device of the present invention is configured bycomprising: a laser diode for emitting a laser light having a peak wavelength of 360 nm to 420 nm; and a phosphor surface having apredetermined pattern which is formed by arranging phosphor layers intwo dimensional directions, the phosphor layers emitting red, green orblue lights when excited by the laser light, wherein the laser lightscans on the phosphor surface and an image is displayed by a lightexcited by the laser light.

Further, an illumination device of the present invention is configuredby comprising: a laser diode for emitting a laser light having a peakwavelength of 360 nm to 420 nm; and a phosphor film which is formed bymixing a phosphor emitting blue light, a phosphor emitting green lightand a phosphor emitting red light when the phosphors are excited by thelaser light, wherein a visible light is obtained by radiating the laserlight to the phosphor film.

According to the white LED lamp of this invention, an amount of the UVlight contained in the radiated white light and an amount of heatgenerated from the lamp are small.

Further, according to the backlight of this invention, the amount of UVlight contained in the released light and the amount of heat generatedfrom the white LED lamp are small.

Furthermore, according to the illumination device of this invention, theamount of UV light contained in the released light and the amount ofheat generated from the white LED lamp are small. Therefore, an amountof harmful ultra violet rays leaked from the white LED lamp is small,and a harmful effect against eyes and skin can be excluded. In addition,an amount of heat generated from the illumination device is small, sothat the illumination device is excellent in energy efficiency andenergy-saving performance (energy conservation property).

In particular, according to the display device using the laser diode foremitting a laser light having a peak wavelength of 360 nm to 420 nm isused as an excitation light source, an excited light having a narrowband peak wavelength, so that it is easy to scan the phosphor layer byusing the excited light, whereby a high definition image can beobtained.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a cross sectional view schematically showing a structure of afirst embodiment of a white LED lamp according to the present invention.

FIG. 2 is a cross sectional view schematically showing a structure of asecond embodiment of the white LED lamp according to the presentinvention.

FIG. 3 is a cross sectional view schematically showing a structure of athird embodiment of the white LED lamp according to the presentinvention.

FIG. 4 is a cross sectional view schematically showing a structure of awhite LED lamp according to Comparative Example 2.

FIG. 5 is a perspective view schematically showing one example ofthickness of a transparent resin layer.

FIG. 6 is a perspective view schematically showing one example ofthickness of a phosphor layer.

FIG. 7 is a cross sectional view schematically showing one embodiment ofa display device according to the present invention.

FIG. 8 is a sectional view schematically showing an example of structureof a phosphor layer formed in the display device according to thepresent invention.

FIG. 9 is a cross sectional view schematically showing one embodiment ofan illumination device according to the present invention.

FIG. 10 is a plan view and a cross sectional view schematically showinganother embodiment of an illumination device according to the presentinvention.

FIG. 11 is a plan view schematically showing still another embodiment ofan illumination device according to the present invention.

BEST MODE FOR CARRYING OUT THE INVENTION

The white LED lamp, the backlight, and the illumination device accordingto the present invention will be explained hereunder with reference tothe accompanying drawings.

First Embodiment

FIG. 1 is a cross sectional view schematically showing a firstembodiment of a white LED lamp according to the present invention. Asshown in FIG. 1, the white LED lamp 1 comprises: a substrate 10 providedwith a front surface side electrode 12 as a conductive portion which isprovided on an insulation portion 11; a light emitting diode chipmounted on the front surface side electrode 12 of the substrate 10; atransparent resin layer 30 for sealing the light emitting diode chip 20;and a phosphor layer 40 for covering the transparent resin layer 30.

(Substrate)

The substrate 10 comprises: the insulation portion 11; the front surfaceside electrode 12 provided to the front side of the substrate 10 and arear surface side electrode 13 provided to a rear surface side of thesubstrate 10; and a power-supplying via 14 passing through theinsulation potion 11 so as to establish an electrical connection betweenthe front surface side electrode 12 and the rear surface side electrode13.

(Insulation Portion)

As a material for constituting the insulation portion 11, for example,plate members composed of ceramics such as alumina, aluminum nitride(AlN) or glass epoxy resin or the like are used. When the insulationportion 11 is formed of alumina plate or aluminum nitride plate, athermal conductivity is high, so that a temperature rise of the whiteLED lamp can be suppressed, thus being preferable.

Further, when the insulation portion 11 is composed of glass epoxy resinplate formed with a heat radiation via which is formed by filling asilver paste, a copper paste or the like into a via hole passing throughbetween: an entire portion or a part of a portion among the frontsurface side electrode 12 to which the light emitting diode chip 20 isprovided; and rear surface side electrode 13, a thermal conductivity ishigh, so that the temperature rise of the white LED lamp can besuppressed, thus being also preferable.

An effect of suppressing the temperature rise in the white LED lamp canbe confirmed, for example, by measuring a lowering of a thermalresistance (heat resistance) Rth between a junction portion of the LEDchip and a rear surface of the insulation portion 11. In the presentinvention, the thermal resistance Rth is, for example, 40° C./W or lessper one light emitting diode chip.

(Conductive Portion)

The conductive portion as the front surface side electrode 12 isprovided onto the insulation portion 11 thereby to constitute thesubstrate 10. The front surface side electrode 12 is one conductiveportion of a side onto which the light emitting diode chip is mounted,so that the front surface side electrode 12 is configured as alight-reflective electrode. This light-reflective electrode means anelectrode having a reflectivity of 60% or more with respect to a lighthaving a wavelength of 400 nm when the reflectivity is measured by aspectral reflectometer. As the light-reflective electrode, metalelectrodes composed of Ag, Pt, Ru, Pd and Al or the like can berecommended.

When the front surface side electrode 12 is configured as thelight-reflective electrode, even if a part of a secondary light emittedfrom the phosphor powder 42 is reflected to a side of the front surfaceside electrode 12 or even if a part of a primary light emitted from thelight emitting diode chip 20 is reflected at an interface between thetransparent resin layer 30 and the phosphor layer 40 thereby to bereflected to a side of the front surface side electrode 12, thereflected lights are further reflected at the front surface sideelectrode 12, thereby to be reflected to a side of a releasing surface60. As a result, a luminance of the white LED lamp can be increased tobe high.

The rear surface side electrode 13 is not required to have the lightreflecting property unlike the front surface side electrode 12, so thatthe rear surface side electrode 13 can be formed of well known metalmaterials such as Ag, Pt, Ni, Cu, Au or the like.

When the substrate 10 is an alumina substrate using an alumina plate asthe insulation portion 11, or an aluminum nitride substrate using analuminum nitride plate as the insulation portion 11, or a glass epoxysubstrate using an glass epoxy plate as the insulation portion 11 andprovided with a heat radiating via, the substrate 10 has a high thermalconductivity, so that the temperature rise of the white LED lamp can besuppressed, thus being preferable.

(Light Emitting Diode Chip)

The light emitting diode chip (LED chip) 20 is a light emitting diodechip for emitting an UV light to violet light (primary light) having apeak wavelength of 360 nm to 420 nm. As the light emitting diode chip20, for example, InGaN type, GaN type or AlGaN type light emitting diodechips can be exemplified. It is more preferable that the peak wavelengthof the light emitted from the light emitting diode chip ranges from 360nm to 410 nm.

The light emitting diode chip 20 is bonded to the substrate 10 throughbonding agents of various solders such as Au-Sn eutectic solder or thelike or silver paste or the like. Further, an electrode of the lightemitting diode chip is electrically connected to a surface of the frontsurface side electrode 12 by means of a bonding wire 25.

(Transparent Resin Layer)

The transparent resin layer 30 seals the light emitting diode chip 20,and is composed of a first transparent resin hardened substance 31.

The light emitting diode chip 20 normally has a high reflection factor,and has a characteristic of blocking a light within the LED chip 20.Therefore, when a part of the primary light emitted from the lightemitting diode chip is reflected at an interface between the transparentresin layer and the phosphor layer thereby to be reflected to the lightemitting diode chip or when a visible light (secondary light) radiatedfrom the phosphor powder 42 of the phosphor layer 40 is entered into theLED chip 20, these lights are stayed within the LED chip, so that theblocked lights are hardly brought out. As a result, there is posed aproblem such that a luminance is disadvantageously lowered.

The transparent resin layer 30 has a function of preventing thesecondary light emitted from the phosphor layer 40 from being enteredinto the LED chip 20 thereby to suppress to lower the luminance.

The first transparent resin hardened substance 31 is formed by hardening(setting) a resin having a high transparency. As a transparent resin,for example, silicone resins, epoxy resins or the like are recommended.Among the silicone resins, dimethyl silicone resin is particularlypreferable due to its high UV resistance.

The transparent resin layer 30 can be obtained by such a manner that thetransparent resin is poured on the light emitting diode chip 20 and thebonding wire 25, and then the poured resin is heated up to a temperatureof 100 to 160° C. thereby to harden the transparent resin.

In the present invention, a thickness of the transparent resin layer 30means a distance between a surface of the light emitting diode chip 20and an interface 32 of the phosphor layer 40. The thickness of thetransparent resin layer 30 is indicated by reference symbols of t1 to t5or the like as shown in FIG. 5.

The thickness of the transparent resin layer 30 is normally set to 0.1mm or more, preferably to 0.2 mm or more, more preferably to within arange of 0.2 mm to 1.0 mm.

When the thickness of the transparent resin layer 30 is 0.1 mm or more,a luminous efficiency is preferably improved.

On the other hand, when the thickness of the transparent resin layer 30is excessively large, a size of the white LED lamp becomes large, sothat there may be a fear that the white LED lamp becomes unsuitable fora light source of backlight of a liquid crystal display device or alight source for an illumination device. Therefore, it is preferable toset the thickness of the transparent resin layer 30 to 1.0 mm or less sothat the white LED lamp can be incorporated within a size range which issuitable for the light source of the backlight for the liquid crystaldisplay device or the light source for the illumination device.

In the present invention, a wire landing site thickness is defined as adistance between a wire landing site 26 in the transparent resin layer30 and an interface 32 of the phosphor layer 40. The wire landing sitethickness is indicated by a reference symbol of t11 to t5 or the like asshown in FIG. 5.

The wire landing site thickness is preferably set to 0.5 mm or more fromthe viewpoint of protecting the bonding wire 25.

(Phosphor Layer)

The phosphor layer 40 covers the transparent resin layer 30, and thephosphor layer 40 is formed by dispersing the phosphor powder 42 into asecond transparent resin hardened substance 41. The phosphor powder 42receives the primary light emitted from the light emitting diode chip 20and emits a light (secondary light) having a wavelength longer than thatof the primary light.

The second transparent resin hardened substance 41 is formed byhardening (setting) a resin having a high transparency. As thetransparent resin for forming the second transparent resin hardenedsubstance 41, for example, the same resin as the transparent resin usedfor forming the first transparent resin hardened substance 31. Thetransparent resin used for forming the second transparent resin hardenedsubstance 41 and the transparent resin used for forming the firsttransparent resin hardened substance 31 may be the same kind of resin,or may be different to each other.

As the phosphor powder 42 used in the phosphor layer 40, there are useda blue phosphor powder 42B (42) for receiving the primary light emittedfrom the light emitting diode chip 20 and emitting a blue color light, agreen phosphor powder 42G (42) for emitting a green color light, ayellow phosphor powder 42Y (42) for emitting a yellow color light and ared phosphor powder 42R (42( for emitting a red color light, or thelight.

(Blue Phosphor Powder)

As the blue phosphor powder 42B, a blue phosphor powder for emitting ablue color light having a peak wavelength of 430 nm to 460 nm is used.As the blue phosphor powder 42B, for example, a blue phosphor powderhaving a composition expressed by the following equation (1) is used.

(Sr_(1-x-y-z)Ba_(x)Ca_(y)Eu_(z))₅(PO₄)₃Cl   (1)

wherein x, y and z respectively satisfy the relations 0≦x<0.5, 0≦y<0.1,0.005<z<0.1.

When x and y in the equation (1) are respectively within the aboveranges, the wavelength of a light emitted from the blue phosphor powderbecomes suitable to the white LED lamp for an illumination use and abacklight use, thus being preferable.

As the x and y values prescribed in the equation (1) are increasedwithin the above ranges, an amount of light component having a longwavelength is increased in the light emitted from the blue phosphorpowder, so that the white LED lamp becomes more suitable for anillumination use.

In contrast, as the x and y values prescribed in the equation (1) aredecreased within the above ranges, a spectrum width of the light emittedfrom the blue phosphor powder becomes narrow, so that the white LED lampbecomes more suitable for a backlight use.

When z in the equation (1) is within the above range, a luminousefficiency of the blue phosphor powder becomes to be high, thus beingpreferable.

(Green Phosphor Powder)

As the green phosphor powder 42G, a green phosphor powder for emitting agreen color light having a peak wavelength of 490 nm to 575 nm is used.As the green phosphor powder 42G, for example, a green phosphor powdercomposed of europium/ manganese-activated aluminate having a compositionexpressed by an equation (2) is used.

(Br_(1-x-y-z)Sr_(x)Ca_(y)Eu_(z))(Mg_(1-u)Mn_(u))Al₁₀O₁₇   (2)

wherein x, y, z and u respectively satisfy the relations 0≦x<0.2,0≦y<0.1, 0.005<z<0.5, 0.1<u<0.5.

When z and u prescribed in the equation (2) are within the above ranges,a luminous efficiency of the green phosphor powder becomes to be high,thus being preferable.

When z and u prescribed in the equation (2) are within the above ranges,a life and a brightness (luminance) of the green phosphor powder arewell-balanced, thus being preferable.

When x prescribed in the equation (2) exceeds 0.2, there may be a fearof lowering the life of the green phosphor powder. Further, when xprescribed in the equation (2) is equal to zero, a short wavelengthcomponent is increased in the light emitted from the green phosphorpowder, so that there may be a fear of lowering the brightness.

(Yellow Phosphor Powder)

As the yellow phosphor powder 42Y, a yellow phosphor powder for emittinga yellow color light having a peak wavelength of 545 nm to 565 nm isused. As the yellow phosphor powder 42Y, for example, at least one ofyellow phosphor powders having compositions expressed by equation (3)and equation (4) are used.

ZnS: Au_(c)Al_(d)   (3)

wherein c and d respectively satisfy the relations 0.0001<c, d<0.002.

When c and d prescribed in the equation (2) are within the above ranges,a luminous efficiency of the yellow phosphor powder becomes to be high,thus being preferable.

(Sr_(2-x-y-z-u)Ba_(x)Mg_(y)Eu_(z)Mn_(u))SiO₄   (4)

wherein x, y, z and u respectively satisfy the relations 0.1<x<0.4,0.005<y<0.21, 0.05<z<0.3, 0.001<u<0.04.

When x in the equation (4) is within the above range, the wavelength ofa light emitted from the yellow phosphor powder becomes suitable to theillumination use and the backlight use, thus being preferable. Further,as the x value prescribed in the equation (4) is increased within theabove range, the wavelength of the light emitted from the yellowphosphor powder becomes to be short, so that the white LED lamp becomesmore suitable for the backlight use.

When y prescribed in the equation (4) is within the above range, a solidsolution of Mn is sufficiently advanced, thus being preferable.

When z prescribed in the equation (4) is within the above range, theluminous efficiency of the yellow phosphor powder becomes to be high,thus being also preferable.

When u in the equation (4) is within the above range, the wavelength ofthe light emitted from the yellow phosphor powder becomes suitable tothe illumination use and the backlight use, thus being preferable.Further, as the u value prescribed in the equation (4) is increasedwithin the above range, the wavelength of the light emitted from theyellow phosphor powder becomes to be long, so that the white LED lampbecomes more suitable for the illumination use.

(Red Phosphor Powder)

As the red phosphor powder 42R, a red phosphor powder for emitting a redcolor light having a peak wavelength of 620 nm to 780 nm is used. As thered phosphor powder 42R, for example, at least one of a red phosphorpowder composed of europium activated lanthanum oxysulfide having acomposition expressed by equation (5) and a red phosphor powder having acomposition expressed by equation (6) are used.

(La_(1-x-y)Eu_(x)M_(y))₂O₂S   (5)

wherein M is at least one element selected from a group consisting ofSb, Sm, Ga and Sn, while x and y respectively satisfy the relations0.01<x<0.15, 0≦y<0.03.

When M prescribed in the equation (5) is at least one element selectedfrom the group consisting of Sb, Sm, Ga and Sn, the luminous efficiencyof the red phosphor powder becomes to be high, thus being alsopreferable.

(Sr_(x)Ca_(1-x))SiAlN₃:Eu   (6)

wherein x satisfies a relation 0≦x<0.4.

When x in the equation (6) is within the above range, a range ofwavelength of a light emitted from the red phosphor powder becomessuitable, the luminous efficiency is high, and the wavelength range andthe luminous efficiency are well balanced, thus being preferable.Further, as the x value prescribed in the equation (6) is increasedwithin the above range, the wavelength of the light emitted from the redphosphor powder is liable to be short. In contrast, as the x value isdecreased to be small within the above range, the luminous efficiency ofthe red phosphor powder is liable to be high.

An average grain size of the respective phosphor powders 42 (42B, 42G,42Y and 42R) is normally set to 10 μm or more, preferably to 10 to 100μm, more preferably to 20 to 80 μm. In this connection, the averagegrain size means a grain size of D₅₀ indicating a weight-integratedvalue at 50%.

When the average grain size of the respective phosphor powders 42 are 10μm or more, a light extracting efficiency of the white LED lamp isincreased to be high, thus being preferable.

When the average grain size of the phosphor powder 42 is excessivelylarge, phosphor grains are liable to settle down in the phosphor slurryand the slurry becomes non-uniform, so that there may be a fear ofcausing a large scattering in optical characteristics. In contrast, whenthe average grain size of the phosphor powder 42 is less than 10 μm,there may be a fear of lowering a light extracting efficiency.

each of the phosphor powders 42 can be obtained through well-knownmanufacturing method in which a blending ratio of material powders arecontrolled, calcinating conditions such as temperature and time arecontrolled, and resultant calcined body is pulverized or classified.

The phosphor powders 42 is normally prepared by combining three or fourkinds of phosphor powders selected from a blue phosphor powder 42B, agreen phosphor powder 42G, a yellow phosphor powder 42Y, and a redphosphor powder 42R. The phosphor powders 42 are dispersed into aphosphor layer 40. Further, in a case where three kinds of the phosphorpowders 42 for emitting the respective color lights are used incombination, normally, at least the blue phosphor powder 42B and the redphosphor powder 42R are used to be included.

FIG. 1 schematically shows a state where the respective phosphor powders42 (42B, 42G, 42Y and 42R) for emitting the respective color lights aremixed and dispersed into the phosphor layer 40.

For example, the phosphor layer 40 is obtained through a methodcomprising the steps of: mixing a transparent resin and the respectivephosphor powders thereby to prepare respective phosphor slurries inwhich the respective phosphor powders are dispersed into the transparentresin; mixing the respective phosphor slurries thereby to prepare amixed phosphor slurry; coating the mixed phosphor slurry to atransparent resin layer 30; and hardening (curing) the coated slurry. Ata time of preparing the mixed phosphor slurry, the blending ratio of therespective phosphor powders for emitting the respective color lights isadjusted so as to obtain an aimed emitting light color of the secondarylight.

The mixed phosphor slurry normally has a slurry concentration of 40 wt %to 80 wt %, preferably, 50 wt % to 80 wt %. When the slurryconcentration is within the above range, a luminance becomes high and itis easy to coat the slurry onto the transparent resin layer 30, thusbeing preferable.

When the slurry concentration is less than 40 wt %, there may be a fearthat the primary light transmitting the phosphor layer is increased.While, when the slurry concentration exceeds 80 wt %, there may be afear that it becomes difficult to coat the mixed phosphor slurry ontothe transparent resin layer 30.

The mixed phosphor slurry can be hardened (cured) by heating the slurryto a temperature range of 100° C. to 160° C.

In the present invention, a thickness of the phosphor layer 40 means adistance between an interface 32 of the transparent resin layer 30 and afront surface 43 of the phosphor layer 40. The thickness of the phosphorlayer 40 is indicated by reference symbols of T1, T2, T3, T4, T5 or thelike as shown in FIG. 6.

The thickness of the phosphor layer 40 is normally set to 0.1 mm ormore, preferably to 0.1 to 1.5 mm, more preferably to within a range of0.1 mm to 0.8 mm.

When the thickness of the phosphor layer 40 is 0.1 mm or more, it ispossible to suppress a releasing of UV light emitted from the lightemitting diode 20 to outside the white LED lamp 1, and the secondarylight can be effectively extracted, thus being also preferably.

When the thickness of the phosphor layer 40 is less than 0.1 mm, theremay be a fear that the releasing of the UV light emitted from the lightemitting diode 20 to outside the white LED lamp 1 cannot be suppressed.While, when the thickness of the phosphor layer 40 is excessively large,there may be a fear that the extracting efficiency of the secondarylight is lowered.

[Function]

Next, a function of the white LED lamp 1 will be explained.

when the light emitting diode chip 20 is energized by being bappliedwith a power current, then it emits a UV light or a violet light(primary light). This primary light transmits through the transparentresin layer 30 and reaches to the phosphor layer 40, whereby thephosphor powders 42 contained in the phosphor layer 40 emit a blue colorlight, a green color light, a yellow color light and a red color lightor the like. A content ratio of each of the respective phosphor powdersfor emitting the respective color lights is determined so that a colorof a totalized secondary light becomes white color. Therefore, a whitelight emitted from an output surface 60 of the white LED lamp 1satisfies relations of 0.19≦x, y≦0.38 in terms of chromaticity values(x, y) prescribed in XYZ color system.

A part of the primary light (UV light or violet light) emitted from thelight emitting diode chip 20 transmits through the second transparentresin hardened substance 41 of the phosphor layer 40, and then outputtedfrom the white LED lamp 1.

In the white LED lamp 1, an energy amount of the primary light containedin the outputted light is normally suppressed to be 0.4 mW/lm or less.

The present invention specified as a technical index that a primarylight energy per one light flux is 0.4 mW/lm or less. This technicalindex can be obtained in accordance with the following procedures byusing a spectrum F(λ) obtained by various measuring devices such as atotal luminous flux measuring device, a momentary multi-photometrysystem (MCPD) and other measuring devices.

On the basis of an equation (7) hereunder, the spectrum F( )and arelative visibility V(φ) are multiplied together, and then integratedthereby to obtain φ. In this connection, the relative visibility V(φ) isdefined as a visibility which is relatively calculated from a standardvisibility of 1 with respect to a light having a wavelength of 555 nm.

φ=683·∫F(λ)·V(λ)dλ  (7)

On the basis of an equation (8) hereunder, the primary light energy isobtained by integrating the spectrum F(λ) at a range of 360 to 410 nm,thereby to calculate UV.

UV=∫ ₃₆₀ ⁴¹⁰ F(λ)dλ(8)

The primary light energy per light flux can be obtained from acalculation formula: UV/φ.

In the above procedure, even if a unit of F(λ) is W/nm, W/(sr·m²·nm) orno-unit (relative value), the primary light energy per light flux can beobtained

In a case where a blue light is contained in the white light outputtedfrom the white LED lamp 1, a ratio (peak intensity of the primarylight/peak intensity of the blue color light) of the peak intensity ofthe primary light with respect to the peak intensity of the blue colorlight in an emission spectrum is 0.5 or less when an intensity of theprimary light is assumed to be 1 as a reference mark. As a result, aresidual amount of the primary light contained in the outputted light issmall.

In this regard, in a case where a UV absorbing powder is furtherdispersed into the phosphor layer 40, the primary light emitted from thelight emitting diode chip 20 is absorbed by the UV absorbing powderdispersed in the phosphor layer 40, so that it becomes more difficultfor the primary light to be outputted from the output surface 60 of thewhite LED lamp 1.

Further, the white LED lamp 1 exhibits a high luminous efficiency of 20lm/W or more.

Furthermore, when the light reflecting property of the front sideelectrode 12 is low, a part of the secondary lights emitted from thephosphor powders 42 is reflected to a side of the front side electrode12, and a part of the primary lights emitted from the light emittingdiode chip 20 is reflected at the interface between the transparentresin layer 30 and the phosphor layer 40 thereby to be reflected to theside of the front side electrode 12, so that a luminance (brightness) ofthe white LED lamp is lowered. However, the front surface side electrode12 of the white LED lamp is configured by a light reflective electrode,so that the reflected light toward the front surface side electrode 12is reflected to a side of the output surface 60, thus resulting in ahigh luminance.

According to the above white LED lamp 1, the amount of UV lightcontained in the outputted white light is small, so that there is hardlyoccurred a discoloration of an object illuminated by the light outputtedfrom the above white LED lamp 1.

According to the above white LED lamp 1, the luminous efficiency ishigh, so that a power consumption required for obtaining a predeterminedluminance and illumination intensity is not required so much, and heatgeneration is also small.

By the way, the present invention can adopt another structure in which alead frame (not shown) is used in place of the substrate 10, and thewhite LED lamp is mount on a conductive portion of the lead frame. Asthe lead frame, lead frames composed of various metal materials such asCu-type material including Cu—Fe—P alloy, Fe-type material includingFe-42% Ni alloy or the like, are used. Since the lead frame generallyhas a high thermal conductivity, a temperature rise of the white LEDlamp mounted on the lead frame can be suppressed.

Due to above structure, a thermal resistance (heat resistance) Rthbetween: a junction portion of the LED chip which is connected to theconductive portion of the lead frame; and a rear surface of the leadframe can be lowered. In this structure, the thermal resistance Rth is,for example, 40° C./W or less per one light emitting diode chip.

Second Embodiment

FIG. 2 is a cross sectional view schematically showing a structure of asecond embodiment of the white LED lamp according to the presentinvention. The white LED lamp 1A of the second embodiment shown in FIG.2 is configured by using a substrate 10A in place of the substrate 10used in the white LED lamp 1 of the first embodiment shown in FIG. 1.Other elements of the white LED lamp 1A according to the secondembodiments shown in FIG. 2 are the same as those of the white LED lamp1 according to the first embodiments shown in FIG. 1. Therefore, thesame reference numerals are used to denote the same members or elementsas those of the first embodiment, and the detailed explanations of thesemembers or elements are simplified or omitted hereunder.

In this second embodiment, the substrate 10A is used in place of thesubstrate 10, the front surface side electrode 12A is used in place ofthe front surface side electrode 12, and a light reflecting layer 16 isfurther formed to the front surface side electrode 12A.

The front surface side electrode 12A is composed of metal materials suchas Ag, Pt, Ni, Cu, Au or the like. The front surface side electrode 12Ais formed with the light reflecting layer 16 on the surface thereof, sothat the front surface side electrode 12A needs not to be a lightreflective electrode.

As the light reflecting layer 16, for example, a coated layer (coverlayer) containing fine powder or a coated layer composed of metal isused.

As the coated layer containing fine powder, a coated layer containingfine inorganic powder composed of at least one of titanium oxide, bariumsulfate, alumina and silica is used. In this regard, the fine powdermeans a powder having an average grain size of 10 μm or less.

The coated layer containing the fine powder is obtained, for example, bya method comprising the steps of: preparing an inorganic binder such asphosphate type binder, alkali metal silicate or an organic binder suchas silicone resin or the like; and adhering the fine powder onto asurface of the front surface side electrode 12A using the above binders.The coated layer may also be obtained by another method comprising thesteps of: sintering the fine powder thereby to form a sintered body; andfixing the sintered body onto the surface of the front surface sideelectrode 12A.

As the coated layer composed of metal, a coated layer composed of atleast one metal materials selected from Al, Ag, Pt, Ru and Pd is used.The coated layer composed of metal is formed by plating these metalsonto the surface of the front surface side electrode 12A.

[Function]

Next, a function of the white LED lamp 1A will be explained.

The white LED lamp 1A is different from the white LED lamp 1 in only astructural point where the front surface side electrode 12A and thelight reflecting layer 16 are used in place of the front surface sideelectrode 12. Therefore, an explanation for a common function will beomitted or simplified.

As the same manner as in the white LED lamp 1, the white LED lamp 1Aoutputs a white light from an output surface 60.

In the white LED lamp 1A, a part of the second light emitted from thephosphor powder 42 is radiated to the light reflecting layer 16, and apart of the primary light emitted from the light emitting diode chip 20and reflected at an interface between the transparent resin layer 30 andthe phosphor powder 42 is radiated to the light reflecting layer 16.However, these reflected lights are reflected to a side of the outputsurface 60. Therefore, the white LED lamp 1A can exhibit a highluminance as the same manner as in the white LED lamp 1

Further, as the same manner as in the white LED lamp 1, chromaticity ofthe white light outputted from the output surface 60 of the white LEDlamp 1A is within a range of 0.19≦x, y≦0.38 in terms of chromaticityvalues (x, y) prescribed in XYZ color system.

In the white LED lamp 1A, as the same manner as in the white LED lamp 1,an energy amount of the primary light contained in the outputted lightis normally suppressed to be 0.4 mW/lm or less.

In case of the white LED lamp 1A where a blue light is contained in theoutputted white light because a blue phosphor powder is contained in thephosphor layer, as the same manner as in the white LED lamp 1, a ratio(peak intensity of the primary light/peak intensity of the blue colorlight) of the peak intensity of the primary light with respect to thepeak intensity of the blue color light is 0.5 or less, and the white LEDlamp 1A exhibits a high luminous efficiency of 20 lm/W or more.

According to the above white LED lamp 1A, the amount of UV lightcontained in the outputted white light is small, so that there is hardlyoccurred a discoloration of an object illuminated by the light outputtedfrom the above white LED lamp 1A.

According to the above white LED lamp 1A, the luminous efficiency ishigh, so that a power consumption required for obtaining a predeterminedluminance and illumination intensity is not required so much, and heatgeneration is also small.

In also the case of the above white LED lamp 1A, as the same as in theabove white LED lamp 1, the lead frame (not shown) is used in place ofthe substrate 10A, so that it is possible to suppress the temperaturerise of the white LED lamp mounted on the lead frame.

Due to above structure, a thermal resistance (heat resistance) Rthbetween: a junction portion of the LED chip which is connected to theconductive portion of the lead frame; and a rear surface of the leadframe can be lowered. In this structure, the thermal resistance Rth is,for example, 40° C./W or less per one light emitting diode chip.

Third Embodiment

FIG. 3 is a cross sectional view schematically showing a structure of athird embodiment of the white LED lamp according to the presentinvention. With respect to the white LED lamp 1 of the first embodiment,the white LED lamp 1B of the third embodiment shown in FIG. 3 isconfigured to further form a UV absorbing layer 50 onto the surface ofthe phosphor layer 40.

Other elements of the white LED lamp 1B according to the thirdembodiments shown in FIG. 3 are the same as those of the white LED lamp1 of the first embodiments shown in FIG. 1. Therefore, the samereference numerals are used to denote the same members or elements asthose of the first embodiment, and the detailed explanations of thesemembers or elements are simplified or omitted hereunder.

The UV light absorbing layer 50 is formed by dispersing UV lightabsorbing powder into a third transparent resin hardened substance (notshown).

The third transparent resin hardened substance is a product prepared byhardening a transparent resin having a high transparency. As thetransparent resin for forming the third transparent resin hardenedsubstance, for example, the transparent resin as the same one as usedfor forming the second transparent resin hardened substance 41 is used.The transparent resin for forming the third transparent resin hardenedsubstance and the transparent resin for forming the second transparentresin hardened substance 41 may be the same to each other, or may bedifferent to each other. However, when both the transparent resins arethe same, a bonding property between the phosphor layer 40 and the UVabsorbing layer 50 is high, thus being preferable.

The UV light absorbing powder means a powder selectively absorbing UVlight. As the UV light absorbing powder, for example, there can be useda fine inorganic powder composed of at least one of titanium oxide, zincoxide and cerium oxide. In this regard, the fine powder means a powderhaving an average grain size of 0.1 μm or less.

The UV light absorbing layer 50 can be obtained by a method comprisingthe steps of: preparing a UV absorbing powder slurry by mixing atransparent resin with the UV light absorbing powder; coating the UVabsorbing powder slurry onto a surface of the phosphor layer 40; andhardening the coated UV absorbing powder slurry.

The UV absorbing powder slurry has a slurry concentration of 0.2 wt % to50 wt %, preferably, 1 wt % to 10 wt %. When the slurry concentration ofthe UV absorbing powder slurry is within the range of 0.2 wt % to 50 wt%, the UV light absorbing layer 50 can suppress an outgoing of the UVlight emitted from the light emitting diode 20 to outside the white LEDlamp 1B, thus being preferable.

When the UV light absorbing layer 50 is formed, the primary lightemitted from the light emitting diode 20 is absorbed by the UV lightabsorbing powder contained in the UV light absorbing layer 50, so thatit becomes difficult for the primary light to be outputted from theoutput surface 60A of the white LED lamp 1B.

The UV absorbing layer 50 normally has a thickness ranging from 1 μm to200 μm, preferably within a range of 10 μm to 100 μm. When the thicknessof the UV absorbing layer 50 is within the range of 1 μm to 200 μm, itbecomes difficult for the UV light emitted from the light emitting diode20 to be outputted from the output surface 60A of the white LED lamp 1B,and a lowering of the luminance is small, thus being also preferable.

In this regard, the thickness of the UV absorbing layer 50 means adistance between an interface 43 of the phosphor layer 40 and a surfaceof the UV absorbing layer 50.

[Function]

Next, a function of the white LED lamp 1B will be explained.

The white LED lamp 1B is different from the white LED lamp 1 in only astructural point where the UV light absorbing layer 50 is further formedonto a surface of the phosphor layer 40. Therefore, an explanation for acommon function will be omitted or simplified.

As the same manner as in the white LED lamp 1, the white LED lamp 1Boutputs a white light from an output surface 60A.

In the white LED lamp 1B, since the UV light absorbing layer 50 isfurther formed onto a surface of the phosphor layer 40, even if a partof the primary light emitted from the light emitting diode chip 20transmits through the phosphor layer 40, the transmitted primary lightis absorbed by the UV light absorbing powder layer contained in the UVlight absorbing layer 50.

Therefore, it becomes more difficult for the primary light to beoutputted from the output surface 60A of the white LED lamp 1B incomparison with the white LED lamp 1.

Further, as the same manner as in the white LED lamp 1, chromaticity ofthe white light outputted from the output surface 60A of the white LEDlamp 1B is within a range of 0.19≦x, y≦0.38 in terms of chromaticityvalues (x, y) prescribed in XYZ color system.

In the white LED lamp 1B, as the same manner as in the white LED lamp 1,an energy amount of the primary light contained in the outputted lightis normally suppressed to be 0.4 mW/lm or less.

In case of the white LED lamp 1B where a blue light is contained in theoutputted white light because a blue phosphor powder is contained in thephosphor layer, as the same manner as in the white LED lamp 1, a ratio(peak intensity of the primary light/peak intensity of the blue colorlight) of the peak intensity of the primary light with respect to thepeak intensity of the blue color light is 0.5 or less, and the white LEDlamp 1A exhibits a high luminous efficiency of 20 lm/W or more.

According to the above white LED lamp 1B, the amount of UV lightcontained in the outputted white light is small, so that there is hardlyoccurred a discoloration of an object illuminated by the light outputtedfrom the above white LED lamp 1A.

According to the above white LED lamp 1B, the luminous efficiency ishigh, so that a power consumption required for obtaining a predeterminedluminance and illumination intensity is not required so much, and heatgeneration is also small.

In also the case of the above white LED lamp 1B, as the same as in theabove white LED lamp 1, the lead frame (not shown) is used in place ofthe substrate 10, so that it is possible to suppress the temperaturerise of the white LED lamp mounted on the lead frame.

Due to above structure, a thermal resistance (heat resistance) Rthbetween: a junction portion of the LED chip which is connected to theconductive portion of the lead frame; and a rear surface of the leadframe can be lowered. In this structure, the thermal resistance Rth is,for example, 40° C./W or less per one light emitting diode chip.

A backlight of the present invention has a structure in which the abovewhite LED lamp is used as a light source of a liquid crystal displaydevice.

The backlight of the present invention may be configured to comprise:for example, a light source unit assembled by linearly arranging aplurality of the white LED lamps in a lateral direction; and a lightguide plate for receiving near stripe-shaped lights radiated from thelight source unit and for outputting the lights such that the lightguide plate receives the lights from a side surface thereof and outputsthe lights from a front surface thereof.

According to the backlight of the present invention, the above white LEDlamps are used as a light source, the white LED lamps hardly output UVlight, and a heat radiation is also small. Therefore, even if the whiteLED lamps are used as the light source for the liquid crystal displaydevice, a yellow-discoloration would not occur to the light guide plateor a luminance-improving film, so that a lowering of luminance of theliquid crystal display device or an abnormal chromaticity is hardlyoccurred.

An illumination device of the present invention has a structure in whichthe above white LED lamp is used as a light source.

The illumination device of the present invention can be configured tohave a structure in which a plurality of the above white LED lamps arearranged in a form of linear pattern, grid-pattern or radial pattern, orthe plurality of the white LED lamps are arranged in a form of combiningthese patterns.

According to the illumination device of the present invention, the abovewhite LED lamps are used as a light source, the white LED lamps hardlyoutput UV light, and a heat radiation is also small. Therefore, anobject illuminated by the white LED lamps would not be damaged, and theyellow-discoloration would not occur to the object. As a result, theillumination device of the present invention is effective in a casewhere the object to be illuminated is an article on exhibition of apicture gallery or an art museum. Namely, the illumination device of thepresent invention is suitable as a light source for the picture galleryand the art museum.

Further, a light emitting device of the present invention is configuredby comprising: a laser diode for emitting a laser light having a peakwave length of 360 nm to 420 nm; and a phosphor layer for being excitedby the laser light and emitting blue, green and red lights. A basicstructure of the light emitting device of the present invention is thesame as that of the white LED lamp, and the light emitting device isconfigured by combining a plurality of aforementioned white LED lamps.

Furthermore, a display device of the present invention is configured bycomprising: a laser diode for emitting a laser light having a peak wavelength of 360 nm to 420 nm; and a phosphor screen having a predeterminedpattern which is formed by arranging phosphor layers in two dimensionaldirections, the phosphor layers emitting red, green or blue lights whenexcited by the laser light, wherein the laser light scans on thephosphor screen and an image is displayed by a light excited by thelaser light.

The display device of the present invention is configured, for example,as shown in FIG. 7. Namely, the display device is configured tocomprise: a light source 101 composed of a one-dimensional displayelement 102 for receiving a light outputted from the light source 101and for outputting an image light; a fixed reflection mirror 104 forreflecting the image light outputted from the one-dimensional displayelement 102 through a projection lens 103; a movable reflection mirror(polygon mirror) 105 for further reflecting the image light reflected bythe fixed reflection mirror 104; and a screen 106 for displaying theimage light reflected by the movable reflection mirror (polygon mirror)105 and for displaying the image light as two-dimensional image.

Above constitutional elements are arranged in a thin casing (crystalliquid projector) having a thickness of about 100 mm. As shown in FIG.8, the above screen 106 is formed with phosphor layers 108 forrespectively emitting three colors of BGR lights, and the phosphorlayers 108 formed on a glass substrate are compartmentalized to eachother by black stripes.

The display device of the present invention is configured to comprise: aphosphor screen formed in a predetermined pattern and formed with thephosphor layers for respectively emitting blue (B), green (G), red (R)lights; and a ultraviolet laser light generating source 109 forgenerating.a near-ultraviolet UV laser light having a wavelength of 365nm to 420 nm so as to excite the phosphor layers and output the BGRlights. FIG. 8 shows a principle of this display device 100. At first,the laser light generated from the ultraviolet laser light generatingsource 109 excites the BGR phosphors formed in stripe-shapes thereby toemit BGR lights. The emitted lights transmit through a glass-liketransparent plate formed with BGR phosphor stripes, and the transmittedlights are recognized as image at a side oppose to a side of the UVlight generating source 109. In principle, the display device has asystem similar to that of a Braun tube.

As the UV light generating source, for example, there can be used asolid-state laser (LD) using compound semiconductors such as galliumnitride, as gallium-indium nitride, as gallium-aluminum nitride, whichhave been remarkably advanced in recent years.

As the same as electron beam in Braun tube, a laser beam (laser light)is scanned on the phosphor stripes from right to left or up and downthereby to form the image. As the beam scanning method, there can beadopted: a method in which a moving direction of a pedestal to which thelaser diode is fixed is electrically or magnetically controlled; or amethod in which an emitting direction of the laser beam emitted from thelaser diode is controlled by a mirror such as the polygon mirror.

As the laser light scanning method, there can be adopted: a method inwhich BGR phosphor stripes are scanned by one laser beam as shown inFIG. 8; or a method in which each of the BGR phosphor stripes is scannedand excited by one laser beam.

At the time of exciting the BGR phosphor stripes by the laser beam,there may be a case where an exciting portion of the respective phosphorstripes is slightly deviated in accordance with portions of the phosphorscreen, or one stripe runs over the laser beam in accordance with adiameter size of the laser beam. In case of occurring this situation,the phosphor stripe other than the phosphor stripes for emitting aimedcolors is excited, so that a grade (quality level) of the image islowered. This defect can be improved by forming a blackish non-lightemitting stripe to a portion between the adjacent BGR phosphor stripes,Further, the deviation of a spot to which the laser beam is radiated andan influence of the run-over of the laser beam diameter can bedecreased, thereby to greatly improve a contrast property the image.

Further, in order to prevent the lowering the image quality, there canbe also adopted a countermeasure such that a black-colored plate (blackcolored non-light emitting layer) formed with perforations in a stripedpattern, dotted pattern, or grid pattern is disposed to a portion closeto the phosphor screen. The effect of this black-colored plate is thatwhen the deviation of the spot to which the laser beam is radiated andthe run-over of the laser beam diameter are occurred, unnecessaryportion of the laser beam diameter is cut by the black-colored plate andthe laser beam is radiated to only a portion of the phosphor stripe foremitting aimed color light. The black colored non-light emitting layer)to be formed at a portion between the respective colors of the phosphorstripes can be formed by using a black substance such as, for example,carbon black.

Further, the black-colored plate disposed to the portion close to thephosphor screen can be formed by working, for example, a carbon plate,or a resin sheet, and a carbon fiber into which a carbon black pigmentis mixed is used. The black-colored plate is preferably to be thin.However, the black-colored plate may be also worked such that athickness of only a portion close to the perforation (hole) throughwhich the laser beam passes is worked to be thin.

As the phosphor, it is preferable to use a phosphor which iswell-excited by the laser beam having a wavelength of 365 nm to 420 nm.Concretely, it is preferable to use phosphors having the followingcomposition ranges.

That is, as the blue phosphor (blue light emitting phosphor), it ispreferable to use a phosphor for emitting the blue light having at leastone composition expressed by following general formulas:

(Sr_(1-x-y-z)Ba_(x)Ca_(y)Eu_(z))_(5 (PO) ₄)₃Cl

wherein x, y and z respectively satisfy the relations x, y<0.3 and0.001<z<0.2;

(Ba_(1-x), Eu_(x))Mg Al₁₀O₁₇

wherein x satisfies the relation 0.01<x<0.3; and

(Ba_(3-x-y), Sr_(x), Eu_(y))Mg_(z)Si₂O₈

wherein x, y and z respectively satisfy the relations 0≦x<2.9,0.02<y<0.4, 0.95<z<1.4.

On the other hand, as the phosphor for emitting the green light, it ispreferable to use phosphors having at least one composition expressed bythe following general formulas:

(Ba_(1-x), Eu_(x))(Mg_(1-y), Mn_(y))Al₁₀O₁₇

wherein x and y respectively satisfy the relations 0.05<x<0.5; and0.1<y<0.6;

(Sr_(2-x-y-z-ω), Ba_(x)Mg_(y), Mn_(z), Eu_(ω))SiO₄

wherein x, y, z and ω respectively satisfy the relations 0.05<x<1,0≦y<0.2, 0≦z<0.009, 0.03<ω<0.3;

ZnS:Au_(x), Al_(y)

wherein x and y respectively satisfy the relations 0.0002≦x≦0.015,0.0001≦y≦0.0012;

(Sr_(1-x-y), Ca_(x), Eu_(y))Ga₂S₄

wherein x and y respectively satisfy the relations x<0.2, 0.05<y<0.3;and

(Sr_(3-x)Eu_(x))Si_(y)Al_(z)O_(y)N_(ω)

wherein x, y, z, v and ω respectively satisfy the relations x<0.2,12<y<14, 2<z<4, 1<v<3, 20<ω<22.

On the other hand, as the phosphor for emitting the red light, it ispreferable to use phosphors having at least one composition expressed bythe following general formulas:

(La_(1-x), Eu_(x)Sm_(y))₂O₂S

wherein x and y respectively satisfy the relations 0.01<x<0.2 and0≦y≦0.2;

(Ca_(1-x), Eu_(x))AlSiN₃

wherein x satisfies the relation 0.005<x<0.03;

(Sr_(2-x-y-z-u), Ca_(x)Mg_(y), Eu_(z), Mn_(u))SiO₄

wherein x, y, z and u respectively satisfy the relations 0.05<x<0.4,0.005<y<0.21, 0.05<z<0.3, 0.001<u<0.04; and

(Ba_(3-x-y-z), Sr_(x)Eu_(y), Mn_(z))Mg_(ω)Si₂O₈

wherein x, y, z and w respectively satisfy the relations 0≦x<0.2,0.02<y<0.6, 0.05<z<1.5, 0.95<ω<1.4.

It is preferable that a grain size of the aforementioned blue, green,red phosphors is within a range of 5 to 50 μm. When the grain size ofthe phosphors is less than 5 μm, the luminance of the phosphor becomesin sufficient, and there is a tendency that a production efficiency ofthe phosphors is lowered. In contrast, when the grain size of thephosphors exceeds 50 μm, a density of the phosphor film (layer) islowered, and there is a tendency that an edge portion of the phosphorstripe cannot be accurately formed.

Further, in a case where the display device is used under an outsidelight having a strong intensity, the outside light is radiated to thephosphor screen and reflected, so that the reflected light becomes onefactor of lowering the image quality level. Such problem can be solvedand improved by covering the phosphor with a pigment having the samebody color as that of an emitted light color of the corresponding BGRphosphors.

As the representative pigment, a cobalt blue pigment (cobalt aluminate)is used for the blue phosphor, a viridian green (chromium hydroxide) forthe green phosphor, a compound such as colcothar pigment (ferric oxide)is used for the red phosphor. These pigments absorb almost all of theoutside light, and exhibit an effect of more clearly displaying thedisplayed image. However, in case of the phosphor per se having the bodycolor, it is not always necessary to coat the pigment.

In a case where the display device of the present invention is exposedto a humidity condition, it is preferable that a protection layer havinga high transparency is provided to the phosphor. As a material forachieving the above object, a dense inorganic material is suitable. Forexample, it is effective to use silica, alumina, titania, and compoundor mixture thereof. When these materials are uniformly coated onto thesurface of the phosphor, there can be obtained an effect of suppressinga transmission of moisture and a deterioration of the phosphor can beprevented.

In a case where the stripes of the blue, green, red phosphors are formedto the phosphor screen, it is preferable that a width of the phosphorstripe is set to a range of 10 to 2000 μm. When the stripe width exceeds2000 μm, a tendency of lowering a definition degree of the imageappears.

On the other hand, when the stripe width is less than 10 μm, a purity ofthe emitted light color is lowered due to a miss-landing of the laserlight, and the phosphor stripes are liable to easily peel off at thetime of forming of the phosphor screen, thus being not preferable.

Further, the illumination device of the present invention is configuredto comprises: a laser diode for emitting a laser light having a peakwave length of 360 nm to 420 nm; and a phosphor film which is formed bymixing a phosphor for emitting blue light, a phosphor for emitting greenlight and a phosphor for emitting red light when the phosphors areexcited by the laser light, wherein a visible light is obtained byradiating the laser light to the phosphor film.

Concretely, as shown in FIG. 9, the illumination device of the presentinvention has a structure in which three colors (B, G, R) of phosphorsare coated onto an inner surface of a transparent and cylindrical glasstube 201, thereby to form a phosphor screen (phosphor film) 202. Then, atransparent resin such as silicone containing a laser scattering body203 such as colloidal silica, colloidal alumina, potassium titanate orthe like is prepared, and the transparent resin containing the laserscattering body 203 is imbedded into the cylindrical glass tube 201,thereby to constitute a cylindrical tube type laser illumination device.

Both ends of the cylindrical glass tube 201 are provided with laserlight reflecting mirrors 204 a, 204 b. A laser diode 205 is provided soas to oppose to the laser light reflecting mirrors 204 a. A laser lightoutputted from the laser diode 205 and having a wavelength of 360 nm to420 nm is introduced from a fine hole of the laser light reflectingmirrors 204 a to inside the cylindrical glass tube 201.

In the above illumination device, the laser light outputted from thelaser diode 205 and having the wavelength of 360 nm to 420 nm isscattered by the laser scattering body 203 filled in the cylindricalglass tube 201 toward a tube wall direction, and then radiated to thephosphor screen. The radiated laser light effectively excites thephosphors, so that a white light is effectively outputted to outside thetube.

By the way, it is also possible to configure a plane type laserillumination device 200a by continuously arranging a plurality of aboveillumination devices in a parallel form, as shown in FIG. 10. Further,it is also possible to configure another plane type laser illuminationdevice, which is formed in such a manner that a cylindrical light path206 is spirally formed. A phosphor film (phosphor screen) is formed toone surface or both surfaces of the spirally formed light path 206.Then, as the same manner, one end portion of the light path 206 isarranged with the laser diode 205 thereby to constitute another planetype laser illumination device 200 b as shown in FIG. 11.

Examples

Examples of the present invention will be explained hereunder.

However, the present invention is not limited thereto.

Phosphor powders used in Examples, Comparative Example and ReferenceExample are as follows.

[Blue Phosphor Powders]

(Sr_(0.894)Ba_(0.1)Eu_(0.006))₁₀(PO₄)₆Cl₂(average grain size: 10 μm)  (1)

Predetermined amounts of phosphates of strontium and barium, chloridesof strontium and barium and europium oxide were check-weighed, and mixedby using a ball mill for one hour to prepare a mixture. Thereafter, themixture was calcined in a reducing atmosphere to synthesize a phosphor.The synthesized phosphor was then pulverized by using a mortar, followedby passing a sieve thereby to obtain a blue phosphor having an averagegrain size of 10 μm and having a composition: ((Sr_(0.894)Ba_(0.1)Eu_(0.006))₅(PO₄)₃Cl₂).

In this connection, the average grain size means a grain size D₅₀ whichis measured as a grain size corresponding to a weight accumulated valueof 50%. Hereinafter, the term “average grain size” is used as the samemeaning as define above.

(Sr_(0.42)Ba_(0.48)Ca_(0.01)Eu_(0.09))₁₀(PO₄)₆Cl₂(average grain sizes:12 μm, 8 μm)   (2)

Predetermined amounts of phosphates of strontium and barium, chloridesof strontium and barium and europium oxide were check-weighed, and mixedby using a ball mill to prepare a mixture. Thereafter, the mixture wascalcined in a reducing atmosphere to synthesize a phosphor. Thesynthesized phosphor was then pulverized by using a mortar, followed bypassing a sieve thereby to obtain a blue phosphor having an averagegrain size of 12 μm and having a composition:((Sr_(0.42)Ba_(0.48)Ca_(0.01)Eu_(0.09))₁₀(PO₄)₆Cl₂).

Using the same compound materials, and mixing condition, calciningtemperature, calcining time, pulverizing condition and water washingcondition or the like were controlled, thereby to obtain a blue phosphorhaving an average grain size of 8 μm and having a composition:((Sr_(0.42)Ba_(0.48)Ca_(0.01)Eu_(0.09))₁₀(PO₄)₆Cl₂).

(Sr_(0.85)Ba_(0.01)Ca_(0.09)Eu_(0.05))₁₀(PO₄)₆Cl₂(average grain sizes:20 μm)   (3)

Predetermined amounts of phosphates of strontium and barium, chloridesof strontium and barium and europium oxide were check-weighed, and mixedby using a ball mill for one hour to prepare a mixture. Thereafter, themixture was calcined in a reducing atmosphere to synthesize a phosphor.The synthesized phosphor was then pulverized by using a mortar, followedby passing a sieve thereby to obtain a blue phosphor having an averagegrain size of 20 μm and having a composition:((Sr_(0.85)Ba_(0.01)Ca_(0.09)Eu_(0.06))₁₀(PO₄)₆Cl₂).

(Sr_(0.44)Ba_(0.49)Ca_(0.02)Eu_(0.05))₁₀(PO₄)₆Cl₂(average grain sizes:40 μm)   (4)

Predetermined amounts of phosphates of strontium and barium, chloridesof strontium and barium and europium oxide were check-weighed, and mixedby using a ball mill for one hour to prepare a mixture. Thereafter, themixture was calcined in a reducing atmosphere to synthesize a phosphor.The synthesized phosphor was then pulverized by using a mortar, followedby passing a sieve thereby to obtain a blue phosphor having an averagegrain size of 40 μm and having a composition: ((Sr_(0.44)Ba_(0.49 l Ca)_(0.02)Eu_(0.05))₁₀(PO₄)₆Cl₂).

[Green Phosphor Powders]

(Ba_(0.32)Sr_(0.19)Ca_(0.01)Eu_(0.48))(Mg_(0.89)Mn_(0.11))Al₁₀O₁₇(averagegrain size: 11 μm)   (1)

Carbonates of each of Ba, Sr, Ca and Mn, Eu oxide, Mg oxide, Al oxidewere blended in a predetermined composition ratio, and mixed by using aball mill for one hour to prepare a mixture. Thereafter, the mixture wascalcined in a reducing atmosphere to synthesize a phosphor. Thesynthesized phosphor was then pulverized by using a mortar, followed bypassing a sieve thereby to obtain a green phosphor having an averagegrain size of 11 μm and having a composition:((Ba_(0.32)Sr_(0.19)Ca_(0.01)Eu_(0.48))(Mg_(0.89)Mn_(0.11))Al₁₀O₁₇).

(Ba_(0.975)Sr_(0.01)Ca_(0.009)Eu_(0.006))(Mg_(0.51)Mn_(0.49))Al₁₀O₁₇(averagegrain size: 22 μm)   (2)

Carbonates of each of Ba, Sr, Ca and Mn, Eu oxide, Mg oxide, Al oxidewere blended in a predetermined composition ratio, and mixed by using aball mill for one hour to prepare a mixture. Thereafter, the mixture wascalcined in a reducing atmosphere to synthesize a phosphor. Thesynthesized phosphor was then pulverized by using a mortar, followed bypassing a sieve thereby to obtain a green phosphor having an averagegrain size of 22 μm and having a composition:((Ba_(0.975)Sr_(0.01)Ca_(0.009)Eu_(0.06))(Mg_(0.51)Mn_(0.49))Al₁₀O₁₇).

(Ba_(0.799)Sr_(0.1)Ca_(0.001)Eu_(0.1))(Mg_(0.7)Mn_(0.3))Al₁₀O₁₇(averagegrain size: 25 μm)   (3)

Carbonates of each of Ba, Sr, Ca and Mn, Eu oxide, Mg oxide, Al oxidewere blended in a predetermined composition ratio, and mixed by using aball mill for one hour to prepare a mixture. Thereafter, the mixture wascalcined in a reducing atmosphere to synthesize a phosphor. Thesynthesized phosphor was then pulverized by using a mortar, followed bypassing a sieve thereby to obtain a green phosphor having an averagegrain size of 25 μm and having a composition:((Ba_(0.799)Sr_(0.1)Ca_(0.001)Eu_(0.1))(Mg_(0.7)Mn_(0.3))Al₁₀O₁₇).

(Ba_(0.975)Sr_(0.01)Ca_(0.009)Eu_(0.006))(Mg_(0.7)Mn_(0.3))Al₁₀O₁₇(averagegrain size: 8 μm)   (4)

Carbonates of each of Ba, Sr, Ca and Mn, Eu oxide, Mg oxide, Al oxidewere blended in a predetermined composition ratio, and mixed by using aball mill for one hour to prepare a mixture. Thereafter, the mixture wascalcined in a reducing atmosphere to synthesize a phosphor. Thesynthesized phosphor was then pulverized by using a mortar, followed bypassing a sieve thereby to obtain a green phosphor having an averagegrain size of 8 μm and having a composition:((Ba_(0.975)Sr_(0.01)Ca_(0.009)Eu_(0.006))(Mg_(0.7)Mn_(0.3))Al₁₀O₁₇).

[Yellow Phosphor Powders]

ZnS:Au_(0.0002)Al_(0.0002)(average grain size: 22 μm)   (1)

Predetermined amounts of gold (Au) and aluminum (Al) materials weremixed with ZnS grains to prepare a mixture. Thereafter, the mixture wascalcined thereby to obtain a yellow phosphor having an average grainsize of 22 μm and having a composition: (ZnS:Au_(0.0002)Al_(0.0002)).

(Sr_(1.58)Ba_(0.11)Mg_(0.2)Eu_(0.1)Mn_(0.01))SiO₄(average grain size: 30μm)   (2)

Carbonates of each of Ba, Sr and Mn, Eu oxide, Mg oxide were blended ina predetermined composition ratio, and mixed by using a ball mill forone hour to prepare a mixture. Thereafter, the mixture was calcined in areducing atmosphere to synthesize a phosphor. The synthesized phosphorwas then pulverized by using a mortar, followed by passing a sievethereby to obtain a yellow phosphor having an average grain size of 11μm and having a composition:((Sr_(1.58)Ba_(0.11)Mg_(0.2)Eu_(0.1)Mn_(0.01))SiO₄).

[Red Phosphor Powders]

(La_(0.98)Eu_(0.02))₂O₂S (average grain size: 10 μm)   (1)

Predetermined amounts of lanthanum oxide and europium oxide were mixedwith sulfa powder to prepare a mixture. Thereafter, the mixture wascalcined thereby to obtain a red phosphor having an average grain sizeof 10 μm and having a composition: (La_(0.98)Eu_(0.02))₂O₂S.

(La_(0.86)Eu_(0.14))₂O₂S (average grain size: 7 μm)   (2)

Predetermined amounts of lanthanum oxide and europium oxide were mixedwith sulfa powder to prepare a mixture. Thereafter, the mixture wascalcined thereby to obtain a red phosphor having an average grain sizeof 10 μm and having a composition: (La_(0.86)Eu_(0.14))₂O₂S.

(La_(0.859)Eu_(0.14)Ga_(0.001))₂O₂S (average grain size: 40 μm)   (3)

Predetermined amounts of lanthanum oxide, gallium oxide and europiumoxide were mixed with sulfa powder to prepare a mixture. Thereafter, themixture was calcined thereby to obtain a red phosphor having an averagegrain size of 40 μm and having a composition:(La_(0.859)Eu_(0.14)Ga_(0.001))₂O₂S.

(Sr_(0.39)Ca_(0.61))SiAlN₃:Eu (average grain size: 18 μm)   (4)

Predetermined amounts of strontium nitride, calcium nitride, siliconnitride aluminum nitride and europium nitride were mixed to prepare amixture. Thereafter, the mixture was calcined thereby to obtain a redphosphor having an average grain size of 18 μm and having a composition:(Sr_(0.39)Ca_(0.61))SiAlN₃:Eu.

(Sr_(0.01)Ca₀₉₉)SiAlN₃:Eu (average grain size: 25 μm)   (5)

Predetermined amounts of strontium nitride, calcium nitride, siliconnitride aluminum nitride and europium nitride were mixed to prepare amixture. Thereafter, the mixture was calcined thereby to obtain a redphosphor having an average grain size of 25 μm and having a composition:(Sr₀₀₁ Ca₀₉₉)SiAlN₃:Eu.

Example 1 [Preparation of White LED Lamp]

The following procedures of “mounting of light emitting diode chip”,“forming of transparent resin layer”, “preparation of phosphor slurry”and “forming of phosphor layer” were conducted thereby to manufacture awhite LED lamp.

(Mounting of Light Emitting Diode Chip)

Among two Ag electrodes provided to a surface of an aluminum nitridesubstrate, InGaN type light emitting diode chip (length:0.4 mm×width:0.4mm×height:0.15 mm) was mounted and adhered onto a surface of one Agelectrode using an AuSn solder.

A top portion of this light emitting diode chip and a surface of anotherAg electrode were electrically connected to each other using a bondingwire. Both the two Ag electrodes are light reflecting electrodes eachhaving a glitter surface.

(Forming of Transparent Resin Layer)

Using a dimethyl silicone resin, the light emitting diode chip and thewire bonding were sealed by the transparent resin thereby to form atransparent resin layer. That is, at first, a rectangular-shaped moldingdie having a rectangular shape in section, which is referred to as “afirst rectangular-shaped molding die”, was used. The firstrectangular-shaped molding die was disposed on the aluminum nitride(AlN) substrate so that the light emitting diode chip and the bondingwire were arranged in the first rectangular-shaped molding die.

Next, the silicone resin was poured in the first rectangular-shapedmolding die, followed by heat-treating the silicone resin at atemperature of 140° C. for 10 minutes thereby to harden (cure) thesilicone resin. After the silicone resin was hardened, when the firstrectangular-shaped molding die, was removed, there could be obtained asealed product (substance) having a rectangular-parallelepiped-shape,wherein the light emitting diode chip and the bonding wire were sealedby the transparent resin. Each of thicknesses t1, t2, t3, and t4 of thetransparent resin were 0.2 mm, while a thickness t5 of the transparentresin layer was 1.2 mm.

(Forming of Transparent Resin Layer)

The same silicone resin as used in the formation of the transparentresin layer, and the respective kind of phosphor powders were blended ata predetermined ratio, thereby to prepare the respective phosphorslurries.

The phosphor slurry was prepared for each of BGR phosphors of: a bluephosphor powder (Sr_(0.894)Ba_(0.1)Eu_(0.006))₁₀(PO₄)₆Cl₂ having anaverage grain size of 10 μm; a green phosphor powder(Ba_(0.32)Sr_(0.19)Ca_(0.01)Eu_(0.48))(Mg_(0.89)Mn_(0.11))Al₁₀O₁₇ havingan average grain size of 11 μm; and a red phosphor powder(La_(0.98)Eu_(0.02))₂O₂ S having an average grain size of 10 μm.

A blending ratio (mixing ratio) of the phosphor powder with respect tothe silicone resin in the phosphor slurry was set to 80 mass % for eachof the blue, green and red phosphor powders.

Table 1 shows kinds of the phosphor powders used for preparing thephosphor slurries.

(Formation of Phosphor Layer)

The three kinds of the phosphor slurries for the respective B, G, Rphosphor powders were mixed at a predetermined mixing ratio so that achromaticity of a light emitted from the LED lamp exhibited achromaticity (x=0.28, y=0.23) in an XYZ color system prescribed by CIE(International Commission on Illumination), thereby to prepare a mixedphosphor slurry. A mixing ratio of a total phosphor powders with respectto the silicone resin was set to 80 mass % which is the same value asthose of the respective B, G, R phosphor slurries.

Next, Using this mixed phosphor slurry, there was manufactured a whiteLED lamp in which a surface of the transparent resin layer of the abovesealed product was covered with a phosphor layer. That is, at first, arectangular-shaped molding die having a rectangular shape in section,which is referred to as “a second rectangular-shaped molding die”, wasused. The second rectangular-shaped molding die was disposed on thealuminum nitride (AlN) substrate so that the above sealed product(substance) was arranged in the second rectangular-shaped molding die.

Next, the mixed phosphor slurry resin was poured (dropped) in the secondrectangular-shaped molding die, followed by heat-treating the mixedphosphor slurry at a temperature of 140° C. for 10 minutes thereby toharden (cure) the mixed phosphor slurry. After the mixed phosphor slurrywas hardened, when the second rectangular-shaped molding die wasremoved, there could be obtained a white LED lamp having arectangular-parallelepiped-shape, wherein the light emitting diode chipand the wire bonding were covered with the transparent resin layer andthe phosphor layer. Each of thicknesses T1, T2, T3, T4 and T5 of thephosphor layer of the white LED lamp were 0.1 mm.

[Evaluation of White LED Lamp]

(Evaluation of Emission Property of White LED Lamp)

With respect to thus manufactured white LED lamp, light emissionproperties were measured and evaluated by using a total luminous fluxmeasuring device (SMLS, manufactured by Labsphere Co., Ltd.) and amomentary multiple photometry system (MCPD, manufactured by OtsukaElectron Co., Ltd.

A current of 30 mA was applied to the white LED lamp thereby to measurea voltage. As a result, the voltage was 3.3 V.

An outgoing light emitted from the white LED lamp had a light flux of 2lm, and x value was 0.28 and y value was 0.23 in terms of thechromaticity (x, y) in XYZ color system of CIE.

The light outputted from the white LED lamp contained a residual primarylight having an emission peak wavelength of 399 nm and a peak intensityof 0.032 mW/nm at a current of 30 mA. The residual primary light means apart of light emitted from the light emitting diode chip and outputtedfrom the white LED lamp. Among the spectrum of the light outputted fromthe white LED lamp, when a spectrum intensity (a spectrum intensity ofthe residual primary light) of a wavelength ranging from 360 nm to 410nm was integrated, an energy of the residual primary light was 0.58 mW.

Further, the light outputted from the white LED lamp contained a bluelight (a secondary light emitted from the blue phosphor powder) having apeak wavelength of 447 nm and an emission peak intensity of 0.10 mW/nmat a current of 30 mA.

Based on the above data, a luminous efficiency of the white LED lamp, anenergy of a light having a wavelength ranging from 360 nm to 410 nm pertotal luminous flux (hereinafter, referred to as “an energy of theresidual primary light per total luminous flux”), and a ratio of anemission peak intensity of the residual primary light with respect to anemission peak intensity of the blue color light (an emission peakintensity of the residual primary light/an emission peak intensity ofthe blue color light) (hereinafter, referred to as “a peak intensityratio”) were calculated.

The luminous efficiency was calculated to be 20 lm/W from a calculationformula of 2 lm/(30 mA·3.3V)). Further, the energy of the residualprimary light per total luminous flux was calculated to be about 0.3mW/lm from a calculation formula of 0.58 mW/2 lm.

The peak intensity ratio was calculated to be 0.32 from a calculationformula of (0.032 mW /nm) to (0.10 mW/nm).

Furthermore, with respect to the white LED lamp, a junction temperatureTj of the light emitting diode chip was measured by using a ΔVf method.Concretely, under a state where the white LED lamp was held in the air,and measuring conditions were set as follows: a measuring current was100 μm; a heating current was 30 mA; a heating time was 30 minutes; anda time interval from a time when the heating current was OFF to a timewhen the measuring current was ON was set to 200 μsec, thereby tomeasure the junction temperature Tj. In addition, with respect to thewhite LED lamp, a temperature Ts of a rear surface of the substrate whenapplying the heating current was measured by means of a thermo couple.

Further, with respect to the white LED lamp, a thermal resistance Rthbetween the junction portion and the rear surface of the substrate wasalso calculated. The thermal resistance Rth was calculated by usingabove the junction temperature Tj and the temperature of the rearsurface of the substrate. The thermal resistance Rth was calculated tobe 7° C./W from a calculation formula of (Tj−Ts)/(30 mA·3.3 V).

A part of the measured results are indicated in Table 2.

(Evaluation of Yellow Discoloration for Brightness Enhancement Film)

16 pieces of thus obtained white LED lamps were mounted on a copper-cladliquid crystal polymer laminated plate by using a Pb-free solder. Thusobtained FPC board (flexible printed-circuit board) was adhered to aheat sink comprising aluminum-fins by using a thermal conductiveadhesive agent (manufactured by Sun-Hayato CO., Ltd). Onto these whiteLED lamps, a sheet-shaped and resin-formed luminance increasing film(brightness enhancement film: DBEF-D400; manufactured by Sumitomo 3-MCo., Ltd.) was disposed. Thereafter, under this state, the white LEDlamps ware turned on, under operating conditions for an environmentaltemperature was 90° C. and a current of 30 mA.

After the white LED lamps were turned on for 2000 hours, a transmissionfactor of the brightness enhancement film with respect to a light havinga wavelength of 400 nm was measured. As a result, a yellow discolorationwas not observed at all even after turning on the lamps for 2000 hours,and the transmission factor after turning on the lamps for 2000 hourswas 97% in comparison with the transmission factor of 100% at a timebefore turning on the lamps.

Ratios of the transmission factors after turning on the lamps for 2000hours with respect to the transmission factors before turning on thelamps were indicated in Table 2.

Reference Example 1

A commercially available liquid crystal module was disassembled therebyto take out a CCFL (Cold Cathode Fluorescent Lamp). The same procedureswere repeated except that the cold cathode fluorescent lamp was used inplace of the white LED lamp thereby to evaluate the yellow discolorationof the brightness enhancement film. As a result, the yellowdiscoloration was hardly observed even after turning on the lamps for2000 hours, and the transmission factor after turning on the lamps for2000 hours was 90% in comparison with the transmission factor of 100% ata time before turning on the lamps.

Example 2

[Preparation of White LED Lamp]

The following procedures of “mounting of light emitting diode chip”,“forming of transparent resin layer”, “preparation of phosphor slurry”and “forming of phosphor layer” were conducted thereby to manufacture awhite LED lamp.

(Mounting of Light Emitting Diode Chip)

Among two Pt electrodes provided to a surface of a glass epoxy resinsubstrate (FR-4), the light emitting diode chip as the same one as usedin Example 1 was mounted and adhered onto a surface of one Pt electrodeby using an Ag paste.

A top portion of this light emitting diode chip and a surface of anotherPt electrode were electrically connected to each other using a wirebonding. Both the two Pt electrodes are light reflecting electrodes eachhaving a glitter surface.

(Forming of Transparent resin Layer)

The same procedures as in Example 1 were conducted except that thethicknesses t1, t2, t3, and t4 of the transparent resin layer wererespectively set to 0.3 mm, thereby to seal the light emitting diodechip and the bonding wire by the transparent resin, so that atransparent resin layer was formed.

(Forming of Transparent Resin Layer)

The same silicone resin as used in the formation of the transparentresin layer of Example 1, and the respective kind of phosphor powderswere blended at a predetermined ratio, thereby to prepare the respectivephosphor slurries.

The phosphor slurry was prepared for each of B, G, Y, R phosphors of: ablue phosphor powder ((Sr_(0.42)Ba_(0.48)Ca_(0.01)Eu_(0.09))₁₀(PO₄)₆Cl₂)having an average grain size of 12 μm; a green phosphor powder((Ba_(0.976)Sr_(0.01 l Ca)_(0.009)Eu_(0.006))(Mg_(0.51)Mn_(0.49))Al₁₀O₁₇) having an average grainsize of 22 μm; a yellow phosphor powder (ZnS:Au_(0.0002)Al_(0.0002))having an average grain size of 22 μm; and a red phosphor powder((Sr_(0.39)Ca_(0.61))SiAlN₃:Eu) having an average grain size of 18 μm.

A blending ratio (mixing ratio) of the phosphor powder with respect tothe silicone resin in the phosphor slurry was set to 80 mass % for eachof the blue, green, yellow and red phosphor powders.

Table 1 shows kinds of the phosphor powders used for preparing thephosphor slurries.

(Formation of Phosphor Layer)

The four kinds of the phosphor slurries for the respective B, G, Y, Rphosphor powders were mixed at a predetermined mixing ratio so that achromaticity of a light emitted from the LED lamp exhibited achromaticity (x=0.28, y=0.23) in an XYZ color system prescribed by CIE(International Commission on Illumination), thereby to prepare a mixedphosphor slurry. A mixing ratio of a total phosphor powders with respectto the silicone resin was set to 80 mass % which is the same value asthose of the respective B, G, Y, R phosphor slurries.

Next, Using this mixed phosphor slurry, the same procedures as inExample 1 were repeated except that each of thicknesses T1, T2, T3, T4and T5 of the phosphor layer of the white LED lamp were set to 0.2 mmthereby to manufacture a white LED lamp.

[Evaluation of White LED Lamp]

(Evaluation of Emission Property of white LED Lamp)

With respect to thus manufactured white LED lamp, as the same manner asin Example 1, the light emission properties were measured and evaluated.

An outgoing light emitted from the white LED lamp had a light flux of 4lm, and x value was 0.28 and y value was 0.23 in terms of thechromaticity (x, y) in XYZ color system of CIE.

As the same as in Example 1, the light outputted from the white LED lampcontained a residual primary light having an emission peak wavelength of399 nm and a peak intensity of 0.0026 mW/nm at a current of 30 mA.

Further, the light outputted from the white LED lamp contained a bluelight having an emission peak wavelength of 452 nm and an emission peakintensity of 0.08 mW/nm at a current of 30 mA.

Based on the above data, as the same manner as in Example 1, a luminousefficiency of the white LED lamp, an energy of a residual primary lightper total luminous flux, and a ratio of an emission peak intensity werecalculated.

The luminous efficiency was calculated to be 40 lm. Further, the energyof the residual primary light per total luminous flux was calculated tobe 0.01 mW/lm, and the peak intensity ratio was calculated to be 0.032.

Furthermore, with respect to the white LED lamp, as the same manner asin Example 1, a thermal resistance Rth between the junction portion andthe rear surface of the substrate was also calculated. The thermalresistance Rth was 40° C./W.

A part of the measured results are indicated in Table 2.

(Evaluation of Yellow Discoloration for Brightness Enhancement Film)

The same procedures as in Example 1 were repeated except that 8 piecesof thus obtained white LED lamps were used, thereby to evaluate theyellow-discoloration of the brightness enhancement film.

As a result, a yellow discoloration of the brightness enhancement filmwas not observed at all even after turning on the white LED lamps for2000 hours, and the transmission factor after turning on the lamps for2000 hours was 99% in comparison with the transmission factor of 100% ata time before turning on the lamps.

Ratios of the transmission factors after turning on the lamps for 2000hours with respect to the transmission factors before turning on thelamps were indicated in Table 2.

In view of the above experimental sample (Example 2), the following factwas confirmed. Namely, even in a case where a substrate such as theglass epoxy resin substrate having a poor heat radiating property wasused, when a selection of phosphor powder and a thickness of thephosphor layer were suitably optimized and the energy of the residualprimary light per total light flux was reduced, so that the yellowdiscoloration of the brightness enhancement film could be effectivelysuppressed.

Example 3

[Preparation of White LED Lamp]

The following procedures of “mounting of light emitting diode chip”,“forming of transparent resin layer”, “preparation of phosphor slurry”and “forming of phosphor layer” were conducted thereby to manufacture awhite LED lamp.

(Mounting of Light Emitting Diode Chip)

There was prepared a resin package in which two Cu lead portions (leadframes) subjected to Ag plating were fixed to a package body by usingepoxy resin. Then, the light emitting diode chip as used in Example 1was mounted and adhered onto one Cu lead portion by using an Ag paste.

A top portion of this light emitting diode chip and a surface of anotherCu lead portion were electrically connected to each other using a wirebonding.

(Formation of Transparent Resin Layer)

The same procedures as in Example 1 were conducted except that thethicknesses t1, t2, t3, and t4 of the transparent resin layer wererespectively set to 0.4 mm, thereby to seal the light emitting diodechip and the bonding wire by the transparent resin, so that atransparent resin layer was formed.

(Preparation of Phosphor Slurry)

The same silicone resin as used in the formation of the transparentresin layer of Example 1, and the respective kind of phosphor powderswere blended at a predetermined ratio, thereby to prepare the respectivephosphor slurries.

The phosphor slurry was prepared for each of B, G, R phosphors of: ablue phosphor powder ((Sr_(0.85)Ba_(0.01)Ca_(0.09)Eu_(0.05))₁₀(PO₄)₆Cl₂)having an average grain sizes of 20 μm; a green phosphor powder((Ba_(0. 799) Sr_(0.1)Ca_(0.001)Eu_(0.01))(Mg_(0.7)Mn_(0.3))Al₁₀O₁₇)having an average grain size of 25 μm; and a red phosphor powder((Sr_(0.01 l Ca) ₀₉₉)SiAlN₃: Eu) having an average grain size of 25 μm.

A blending ratio (mixing ratio) of the phosphor powder with respect tothe silicone resin in the phosphor slurry was set to 40 mass % for eachof the blue, green, and red phosphor powders.

Table 1 shows kinds of the phosphor powders used for preparing thephosphor slurries.

(Formation of Phosphor Layer)

The three kinds of the phosphor slurries for the respective B, G, Rphosphor powders were mixed at a predetermined mixing ratio so that achromaticity of a light emitted from the LED lamp exhibited achromaticity (x=0.28, y=0.23) in an XYZ color system prescribed by CIE(International Commission on Illumination), thereby to prepare a mixedphosphor slurry. A mixing ratio of a total phosphor powders with respectto the silicone resin was set to 40 mass % which is the same value asthose of the respective B, G, R phosphor slurries.

Next, Using this mixed phosphor slurry, the same procedures as inExample 1 were repeated except that each of thicknesses T1, T2, T3, T4and T5 of the phosphor layer of the white LED lamp were set to 0.2 mmthereby to manufacture a white LED lamp.

[Evaluation of White LED Lamp]

(Evaluation of Emission Property of white LED Lamp)

With respect to thus manufactured white LED lamp, as the same manner asin Example 1, the light emission properties were measured and evaluated.

An outgoing light emitted from the white LED lamp had a light flux of 3lm, and x value was 0.28 and y value was 0.23 in terms of thechromaticity (x, y) in XYZ color system of CIE.

As the same as in Example 1, the light outputted from the white LED lampcontained a residual primary light having an emission peak wavelength of399 nm and a peak intensity of 0.1 mW/nm at a current of 30 mA.

Further, the light outputted from the white LED lamp contained a bluelight having an emission peak wavelength of 445 nm and an emission peakintensity of 0.2 mW/nm at a current of 30 mA.

On the basis of the above data, as the same manner as in Example 1, aluminous efficiency of the white LED lamp, an energy of a residualprimary light per total luminous flux, and a ratio of an emission peakintensity were calculated.

The luminous efficiency was calculated to be 30 lm/W. Further, theenergy of the residual primary light per total luminous flux wascalculated to be 0.4 mW/lm, and the peak intensity ratio was calculatedto be 0.5.

Furthermore, with respect to the white LED lamp, as the same manner asin Example 1, a thermal resistance Rth between the junction portion andthe rear surface of the substrate was also calculated. The thermalresistance Rth was 4° C./W.

A part of the measured results are indicated in Table 2.

(Evaluation of Yellow Discoloration for Brightness Enhancement Film)

The same procedures as in Example 1 were repeated except that 11 piecesof thus obtained white LED lamps were used, thereby to evaluate theyellow-discoloration of the brightness enhancement film.

As a result, a yellow discoloration of the brightness enhancement filmwas not substantially observed at all even after turning on the whiteLED lamps for 2000 hours, and the transmission factor after turning onthe lamps for 2000 hours was 90% in comparison with the transmissionfactor of 100% at a time before turning on the lamps.

Ratios of the transmission factors after turning on the lamps for 2000hours with respect to the transmission factors before turning on thelamps were indicated in Table 2.

In view of the above experimental sample (Example 3), the following factwas confirmed. Namely, even in a case where the resin package(corresponding to a substrate) having a good heat radiating property wasused, an amount of the energy of the residual primary light per totallight flux was relatively large, so that an effect of suppressing theyellow discoloration of the brightness enhancement film would besomewhat lowered.

Example 4

[Preparation of White LED Lamp]

The following procedures of “mounting of light emitting diode chip”,“forming of transparent resin layer”, “preparation of phosphor slurry”and “forming of phosphor layer” were conducted thereby to manufacture awhite LED lamp.

(Mounting of Light Emitting Diode Chip)

There was prepared an alumina substrate in which seven electrode padseach composed of aluminum were serially arranged. Then, the lightemitting diode chip as used in Example 1 was mounted and adhered ontoeach surface of the electrode pads by using an Ag—Sn eutectic solder.

Each of top portions of these light emitting diode chips and each of thesurfaces of the electrode pads were electrically connected in series toeach other using a bonding wire. Each of the electrode pads is a lightreflecting electrode having a glitter surface.

(Forming of Transparent Resin Layer)

The same procedures as in Example 1 were conducted except that a firstrectangular- shaped molding die capable of simultaneously incorporatingthe seven light emitting diode chips and the bonding wires was used,thereby to seal the light emitting diode chips and the bonding wires bythe transparent resin as the same manner as in Example 1, so that atransparent resin layer was formed.

(Preparation of Phosphor Slurry)

The same silicone resin as used in the formation of the transparentresin layer of Example 1, and the respective kind of phosphor powderswere blended at a predetermined ratio, thereby to prepare the respectivephosphor slurries.

The phosphor slurry was prepared for each of B, Y, R phosphors of: ablue phosphor powder ((Sr_(0.44)Ba_(0.49)Ca_(0.02)Eu_(0.05))₁₀(PO₄)₆Cl₂)having an average grain sizes of 40 μm; a yellow phosphor powder((Sr_(1.58)Ba_(0.11)Mg_(0.2)Eu_(0.1)Mn_(0.01))SiO₄) having an averagegrain size of 30 μm; and a red phosphor powder((La_(0.859)Eu_(0.14)Ga_(0.001))₂O₂S) having an average grain size of 40μm.

A blending ratio (mixing ratio) of the phosphor powder with respect tothe silicone resin in the phosphor slurry was set to 70 mass % for eachof the blue, yellow, and red phosphor powders.

Table 1 shows kinds of the phosphor powders used for preparing therespective phosphor slurries.

(Formation of Phosphor Layer)

The three kinds of the phosphor slurries for the respective B (blue), Y(yellow), R (red) phosphor powders were mixed at a predetermined mixingratio so that a chromaticity of a light emitted from the LED lampexhibited a chromaticity (x=0.28, y=0.23) in an XYZ color systemprescribed by CIE, thereby to prepare a mixed phosphor slurry. A mixingratio of a total phosphor powders with respect to the silicone resin wasset to 70 mass % which is the same value as those of the respective B,Y, R phosphor slurries.

Next, Using this mixed phosphor slurry, the same procedures as in

Example 1 were repeated except that each of thicknesses T1, T2, T3, T4and T5 of the phosphor layer of the white LED lamp were set to 0.7 mmthereby to manufacture a white LED lamp.

[Evaluation of White LED Lamp]

(Evaluation of Emission Property of White LED Lamp)

With respect to thus manufactured white LED lamp, as the same manner asin Example 1, the light emission properties were measured and evaluated.

An outgoing light emitted from the white LED lamp had a light flux of 32lm, and x value was 0.28 and y value was 0.23 in terms of thechromaticity (x, y) in XYZ color system of CIE.

As the same as in Example 1, the light outputted from the white LED lampcontained a residual primary light having an emission peak wavelength of399 nm and a peak intensity of 0.021 mW/nm at a current of 30 mA.

Further, the light outputted from the white LED lamp contained a bluelight having an emission peak wavelength of 451 nm and an emission peakintensity of 0.7 mW/nm at a current of 30 mA.

Based on the above data, as the same manner as in Example 1, a luminousefficiency of the white LED lamp, energy of a residual primary light pertotal luminous flux, and a ratio of an emission peak intensity werecalculated.

The luminous efficiency was calculated to be 45 lm. Further, the energyof the residual primary light per total luminous flux was calculated tobe 0.01 mW/lm, and the peak intensity ratio was calculated to be 0.03.

Furthermore, with respect to the white LED lamp, as the same manner asin Example 1, a thermal resistance Rth between the junction portion andthe rear surface of the substrate was also calculated. As a result, thethermal resistance Rth per one chip was 40° C./ W.

A part of the measured results are indicated in Table 2.

(Evaluation of Yellow Discoloration for Brightness Enhancement Film)

The same procedures as in Example 1 were repeated except that 1 piece ofthus obtained white LED lamp was used, thereby to evaluate the yellow-discoloration of the brightness enhancement film. The white LED lampcontained seven light emitting diodes.

As a result, a yellow discoloration of the brightness enhancement filmwas not substantially observed at all even after turning on the whiteLED lamps for 2000 hours, and the transmission factor after turning onthe lamp for 2000 hours was 99% in comparison with the transmissionfactor of 100% at a time before turning on the lamps.

Ratios of the transmission factors after turning on the lamps for 2000hours with respect to the transmission factors before turning on thelamps were indicated in Table 2.

(Calculation of Lighting Hours until Discoloration)

A damage factor of the white LED lamp was calculated from the spectrumobtained at the time of evaluation of the light emitting property. Thecalculated damage factor was very small to be 0.007, thus beingexcellent.

On the basis of this damage factor, a lighting hours (lighting time)until the discoloration is occurred to a sample, when the light isradiated to the sample, was calculated. The lighting hours until thediscoloration is occurred can be calculated by the following formula:

(MPF peculiar to the sample when using a white fluorescentlamp/illumination intensity)×(damage factor of the white fluorescentlamp/damage factor of the white LED lamp)

In this regard, the term MPF means a “minimum perceptible fading”.

In a case where the sample composed of 85% wool and 15% nylon was used,MPF was 960000 Ix-hour. Further, the damage factor of the whitefluorescent lamp was 0.022. From these data, when the sample wasradiated by a light emitted from the white LED lamp of this Example atan illumination intensity of 750 lx, the lighting hours until thediscoloration was occurred to the sample was calculated by the followingcalculation formula: (960000 lx-hour/750 lx)×(0.022/0.007). As a result,the illumination hours was calculated to be 4023 hours.

In a case where the white fluorescent lamp having the damage factor of0.022 was used in place of the white LED lamp of this Example, alighting hours until the discoloration was occurred to the sample was1280 hours. From this fact, it can be confirmed that the lighting hoursuntil the discoloration was occurred in case of the white LED lamp ofthis Example is about three times larger than that of the whitefluorescent lamp.

Comparative Example 1

[Preparation of White LED Lamp]

The same procedures as in Example 3 were repeated except that each ofthicknesses T1, T2, T3, T4 and T5 of the phosphor layer of the white LEDlamp were set to 0.2 mm thereby to manufacture a white LED lamp.

[Evaluation of White LED Lamp]

(Evaluation of Emission Property of white LED Lamp)

With respect to thus manufactured white LED lamp, as the same manner asin Example 1, the light emission properties were measured and evaluated.

An outgoing light emitted from the white LED lamp had a light flux of3.2 lm, and x value was 0.28 and y value was 0.23 in terms of thechromaticity (x, y) in XYZ color system of CIE.

As the same as in Example 1, the light outputted from the white LED lampcontained a residual primary light having an emission peak wavelength of399 nm and a peak intensity of 0.106 mW/nm at a current of 30 mA.

Further, the light outputted from the white LED lamp contained a bluelight having an emission peak wavelength of 445 nm and an emission peakintensity of 0.2 mW/nm at a current of 30 mA.

Based on the above data, as the same manner as in Example 1, a luminousefficiency of the white LED lamp, an energy of a residual primary lightper total luminous flux, and a ratio of an emission peak intensity werecalculated.

The luminous efficiency was calculated to be 32 lm/W. Further, theenergy of the residual primary light per total luminous flux wascalculated to be 0.45 mW/lm, and the peak intensity ratio was calculatedto be 0.53.

Furthermore, with respect to the white LED lamp, as the same manner asin Example 1, a thermal resistance Rth between the junction portion andthe rear surface of the substrate was also calculated. The thermalresistance Rth was 4° C./W.

A part of the measured results are indicated in Table 2.

(Evaluation of Yellow Discoloration for Brightness Enhancement Film)

The same procedures as in Example 1 were repeated except that 10 piecesof thus obtained white LED lamps were used, thereby to evaluate theyellow-discoloration of the brightness enhancement film.

As a result, a yellow discoloration of the brightness enhancement filmwas observed after turning on the white LED lamps for 2000 hours, andthe transmission factor after turning on the lamps for 2000 hours was87% in comparison with the transmission factor of 100% at a time beforeturning on the lamps.

Ratios of the transmission factors after turning on the lamps for 2000hours with respect to the transmission factors before turning on thelamps were indicated in Table 2.

In view of the above experimental sample (Comparative Example 1), thefollowing fact was confirmed. Namely, in a case where the thickness ofthe phosphor layer is thin, the brightness enhancement film caused theyellow discoloration.

Comparative Example 2

[Preparation of White LED Lamp]

A white LED lamp was manufactured in accordance with the followingprocedures.

Comparative Example 2

[Preparation of White LED Lamp]

The following procedures of “mounting of light emitting diode chip”,“preparation of phosphor slurry” and “forming of phosphor layer” wereconducted thereby to manufacture a white LED lamp.

(Mounting of Light Emitting Diode Chip)

As the same manner as in Example 2, the light emitting diode chip wasmounted and adhered onto the glass epoxy resin substrate.

(Preparation of Phosphor Slurry)

As the same manner as in Example 3, the phosphor slurry was prepared foreach of a blue phosphor powder, a green phosphor powder and a redphosphor powder.

Table 1 shows kinds of the phosphor powders used for preparing thephosphor slurries.

(Formation of Phosphor Layer)

As the same manner as in Example 3, the three kinds of the phosphorslurries for the respective B, G, R phosphor powders were mixed, therebyto prepare a mixed phosphor slurry.

The light emitting diode chip and the bonding wire were sealed by themixed phosphor slurry and a a phosphor layer was formed thereby tomanufacture a white LED lamp. That is, at first, a rectangular-shapedmolding die having a rectangular shape in section, which is referred toas “a first rectangular-shaped molding die”, was used. The firstrectangular-shaped molding die was disposed on a glass epoxy resinsubstrate so that the light emitting diode chip and the bonding wirewere arranged in the first rectangular-shaped molding die.

Next, the mixed phosphor slurry was poured in the firstrectangular-shaped molding die, followed by heat-treating the siliconeresin at a temperature of 140° C. for 10 minutes thereby to harden(cure) the mixed phosphor slurry. After the mixed phosphor slurry washardened, when the first rectangular-shaped molding die, was removed,there could be obtained a white LED lamp having arectangular-parallelepiped-shape, wherein the light emitting diode chipand the bonding wire were sealed by the phosphor layer. Each ofthicknesses T1, T2, T3, T4 and T5 of the phosphor layer of the white LEDlamp were 0.2 mm, while a thickness t5 of the transparent resin layerwas 1.2 mm.

FIG. 4 is a cross sectional view schematically showing a structure ofthus obtained white LED lamp. The white LED lamp 2 shown in FIG. 4 has astructure in which the transparent resin layer formed in the white LEDlamp 1 of the first embodiment shown in FIG. 1 is not formed. Otherelements of the white LED lamp 2 shown in FIG. 4 are the same as thoseof the white LED lamp 1 shown in FIG. 1. Therefore, the same referencenumerals are used to denote the same members or elements as those of thefirst embodiment, and the detailed explanations of these members orelements are simplified or omitted hereunder.

As shown in FIG. 4, the white LED lamp according to the aboveexperimental sample (Comparative Example 2) has a structure in which atransparent resin layer is not formed, and the light emitting diode chip20 and the bonding wire 25 are sealed by the phosphor layer 40.

[Evaluation of White LED Lamp]

(Evaluation of Emission Property of White LED Lamp)

With respect to thus manufactured white LED lamp, light emissionproperties were measured and evaluated as the same manner as in Example1.

An outgoing light emitted from the white LED lamp had a light flux of1.8 lm, and x value was 0.28 and y value was 0.23 in terms of thechromaticity (x, y) in XYZ color system of CIE.

As the same as in Example 1, the light outputted from the white LED lampcontained a residual primary light having an emission peak wavelength of399 nm and a peak intensity of 0.1 mW/nm at a current of 30 mA.

Further, the light outputted from the white LED lamp contained a bluelight having a peak wavelength of 445 nm and an emission peak intensityof 0.2 mW/nm at a current of 30 mA.

As the same manner as in Example 1, on the basis of the above data, theluminous efficiency of the white LED lamp, the energy of the residualprimary light per total luminous flux, and the peak intensity ratio werecalculated.

The luminous efficiency was calculated to be 18 lm/W. Further, theenergy of the residual primary light per total luminous flux wascalculated to be 0.41 mW/lm. Furthermore, the peak intensity ratio wascalculated to be 0.5.

Furthermore, with respect to the white LED lamp, as the same manner asin Example 1, the thermal resistance Rth between the junction portionand the rear surface of the substrate was also calculated. The thermalresistance Rth was 40° C./W.

A part of the measured results are indicated in Table 2.

(Evaluation of Yellow Discoloration for Brightness Enhancement Film)

The same procedures as in Example 1 were repeated except that 18 piecesof thus obtained white LED lamps were used, thereby to evaluate theyellow-discoloration of the brightness enhancement film.

As a result, a yellow discoloration of the brightness enhancement filmwas observed after turning on the white LED lamps for 2000 hours, andthe transmission factor after turning on the lamps for 2000 hours was85% in comparison with the transmission factor of 100% at a time beforeturning on the lamps.

Ratios of the transmission factors after turning on the lamps for 2000hours with respect to the transmission factors before turning on thelamps were indicated in Table 2.

In view of the above experimental sample (Comparative Example 2), thefollowing fact was confirmed. Namely, in a case where the transparentresin layer was not formed, the luminous efficiency wasdisadvantageously lowered, and the brightness enhancement film causedthe yellow discoloration.

In the structure in which the transparent resin layer is formed as inExample 1 or the like, the UV light—violet color light (primary light)emitted from the light emitting diode chip reaches the phosphor powdercontained in the phosphor layer thereby to generate the secondary light.A part of the primary and secondary light is reflected at an interfacebetween the transparent resin layer and the phosphor layer, and thereflected light is then entered into the light emitting diode chip orthe light reflective electrodes.

The primary and secondary light entered into the light emitting diodechip is blocked within the light emitting diode chip because thereflection factor of the light emitting diode chip is large, and theentered light is hardly reflected. In contrast, the primary lightincident into the light reflective electrode is reflected again toward aside of the phosphor layer. As explained above, in case of the white LEDlamp formed with the transparent resin layer, a part of the reflectedlights of the primary and the secondary lights are merely blocked withinthe light emitting diode chip.

In contrast to this, in case of the present experimental sample(Comparative Example 2), since the transparent resin layer is notformed, the phosphor layer is adjacent to the surface of light emittingdiode chip. All of the primary and the second lights reflected at theinterface between the light emitting diode chip and the phosphor layeris incident into the light emitting diode chip, and blocked therein.Therefore, it is supposed that the luminous efficiency was lowered inthe present experimental sample.

In the present experimental sample, the yellow-discoloration wasevaluated under the condition where the number of the white LED lampswas increased so as to secure a necessary amount of light flux whichcompensated for the lowered luminous efficiency of the white LED lamp.

In the present experimental sample, it was supposed that the powerconsumption and the generated heat amount were increased, so that thebrightness enhancement film caused the yellow discoloration by theaction of UV light and heat.

Example 3

[Preparation of White LED Lamp]

Using the white LED lamp obtained in Comparative Example 1, thefollowing procedures of “preparation of UV light absorbing layer slurry”and “forming of UV light absorbing layer” were conducted thereby tomanufacture a white LED lamp.

(Preparation of UV Light Absorbing Layer Slurry)

The same silicone resin as used in the formation of the transparentresin layer of Example 1, and ZnO fine particles having an average grainsize of 10 nm were blended thereby to prepare a UV Light absorbing layerslurry containing 10 mass % of ZnO fine particles.

This UV light absorbing layer slurry was coated onto a surface of thephosphor layer of the white LED lamp obtained in Comparative Example 1.Then, the coated UV light absorbing layer slurry was heat-treated at atemperature of 140° C. for 10 minutes thereby to harden (cure) the mixedphosphor slurry. After the mixed phosphor slurry was hardened. As aresult, there was obtained a white LED lamp having arectangular-parallelepiped-shape, wherein the phosphor layer was coveredwith the UV light absorbing layer. The thickness of the UV lightabsorbing layer was 50 μm.

[Evaluation of White LED Lamp]

(Evaluation of Emission Property of white LED Lamp)

With respect to thus obtained white LED lamp, as the same manner as inExample 1, the light emission properties were measured and evaluated.

An outgoing light emitted from the white LED lamp had a light flux of3.1 lm, and x value was 0.29 and y value was 0.23 in terms of thechromaticity (x, y) in XYZ color system of CIE.

As the same as in Example 1, the light outputted from the white LED lampcontained a residual primary light having an emission peak wavelength of399 nm and a peak intensity of 0.061 mW/nm at a current of 30 mA.

Further, the light outputted from the white LED lamp contained a bluelight having an emission peak wavelength of 445 nm and an emission peakintensity of 0.19 mW/nm at a current of 30 mA.

On the basis of the above data, as the same manner as in Example 1, theluminous efficiency of the white LED lamp, the energy of a residualprimary light per total luminous flux, and the ratio of the emissionpeak intensity were calculated.

The luminous efficiency was calculated to be 31 lm/W. Further, theenergy of the residual primary light per total luminous flux wascalculated to be 0.25 mW/lm, and the peak intensity ratio was calculatedto be 0.32.

Furthermore, with respect to the white LED lamp, as the same manner asin Example 1, the thermal resistance Rth between the junction portionand the rear surface of the substrate was also calculated. The thermalresistance Rth was 4° C./W.

A part of the measured results are indicated in Table 2.

(Evaluation of Yellow Discoloration for Brightness Enhancement Film)

The same procedures as in Example 1 were repeated except that 10 piecesof thus obtained white LED lamps were used, thereby to evaluate theyellow-discoloration of the brightness enhancement film.

As a result, the yellow discoloration of the brightness enhancement filmwas not substantially observed at all even after turning on the whiteLED lamps for 2000 hours, and the transmission factor after turning onthe lamps for 2000 hours was 95% in comparison with the transmissionfactor of 100% at the time before turning on the lamps.

Ratios of the transmission factors after turning on the lamps for 2000hours with respect to the transmission factors before turning on thelamps were indicated in Table 2.

Comparative Example 3

[Preparation of White LED Lamp]

The following procedures of “mounting of light emitting diode chip”,“forming of transparent resin layer”, “preparation of phosphor slurry”and “forming of phosphor layer” were conducted thereby to manufacture awhite LED lamp.

(Mounting of Light Emitting Diode Chip and Forming of Transparent ResinLayer)

As the same manner as in Example 2, the light emitting diode chip wasmounted and adhered onto the glass epoxy resin substrate. Thereafter,the light emitting diode chips and the bonding wires were sealed by thetransparent resin, so that a transparent resin layer was formed.

(Preparation of Phosphor Slurry)

The same silicone resin as used in the formation of the transparentresin layer of Example 1, and the respective kinds of phosphor powderswere blended at a predetermined ratio, thereby to prepare the respectivephosphor slurries.

The phosphor slurry was prepared for each of B, Y, R phosphors of: ablue phosphor powder ((Sr_(0.42)Ba_(0.48)Ca_(0.01)Eu_(0.09))₁₀(PO₄)₆Cl₂)having an average grain sizes of 8 μm; a green phosphor powder((Ba_(0.976)Sr_(0.01)Ca_(0.009)Eu_(0.06))(Mg_(0.7)Mn_(0.3))Al₁₀O₁₇)having an average grain size of 8 μm; and a red phosphor powder((La_(0.86)Eu_(0.14))₂O₂S) having an average grain size of 7 μm.

A blending ratio (mixing ratio) of the phosphor powder with respect tothe silicone resin in the phosphor slurry was set to 80 mass % for eachof the blue, green, and red phosphor powders.

Table 1 shows kinds of the phosphor powders used for preparing therespective phosphor slurries.

(Formation of Phosphor Layer)

The three kinds of the phosphor slurries for the respective B (blue), G(green), R (red) phosphor powders were mixed at a predetermined mixingratio so that a chromaticity of a light emitted from the LED lampexhibited a chromaticity (x=0.28, y=0.23) in an XYZ color systemprescribed by CIE, thereby to prepare a mixed phosphor slurry. A mixingratio of a total phosphor powders with respect to the silicone resin wasset to 80 mass % which is the same value as those of the respective B,G, R phosphor slurries.

Next, Using this mixed phosphor slurry, the same procedures as inExample 1 were repeated except that each of thicknesses T1, T2, T3, T4and T5 of the phosphor layer of the white LED lamp were set to 0.2 mmthereby to manufacture a white LED lamp.

[Evaluation of White LED Lamp]

(Evaluation of Emission Property of White LED Lamp)

With respect to thus manufactured white LED lamp, as the same manner asin Example 1, the light emission properties were measured and evaluated.

An outgoing light emitted from the white LED lamp had a light flux of 1lm, and x value was 0.28 and y value was 0.23 in terms of thechromaticity (x, y) in XYZ color system of CIE.

As the same as in Example 1, the light outputted from the white LED lampcontained a residual primary light having an emission peak wavelength of399 nm and a peak intensity of 0.032 mW/nm at a current of 30 mA.

Further, the light outputted from the white LED lamp contained a bluelight having an emission peak wavelength of 452 nm and an emission peakintensity of 0.07 mW/nm at a current of 30 mA.

On the basis of the above data, as the same manner as in Example 1, aluminous efficiency of the white LED lamp, energy of a residual primarylight per total luminous flux, and a ratio of an emission peak intensitywere calculated.

The luminous efficiency was calculated to be 10 lm. Further, the energyof the residual primary light per total luminous flux was calculated tobe 0.42 mW/lm, and the peak intensity ratio was calculated to be 0.46.

Furthermore, with respect to the white LED lamp, as the same manner asin Example 1, a thermal resistance Rth between the junction portion andthe rear surface of the substrate was also calculated. As a result, thethermal resistance Rth was 40° C./W.

A part of the measured results are indicated in Table 2.

(Evaluation of Yellow Discoloration for Brightness Enhancement Film)

The same procedures as in Example 1 were repeated except that 32 piecesof thus obtained white LED lamps were used, thereby to evaluate theyellow-discoloration of the brightness enhancement film.

As a result, a yellow discoloration of the brightness enhancement filmwas observed after turning on the white LED lamps for 2000 hours, andthe transmission factor after turning on the lamps for 2000 hours was85% in comparison with the transmission factor of 100% at a time beforeturning on the lamps.

Ratios of the transmission factors after turning on the lamps for 2000hours with respect to the transmission factors before turning on thelamps were indicated in Table 2.

In view of the above experimental sample (Comparative Example 3), thefollowing fact was confirmed. Namely, in a case where the average grainsize of the phosphor powder was small, the luminous efficiency wasdisadvantageously lowered and the brightness enhancement film caused theyellow discoloration.

Next, an embodiment of the display device of the present invention inwhich thus prepared white LED is used as a backlight will be explainedmore concretely with reference to the following Examples and ComparativeExamples.

Examples 101-124 and Comparative Examples 101-124

There were prepared the respective blue (B), green (G) and red (R)phosphors each having the following compositions for forming phosphorlayers of the display devices according to Examples and ComparativeExamples.

Example 101

Blue phosphor: (Sr_(0.99)Eu_(0.01))₅(PO₄)₃Cl

Green phosphor: (Ba_(0.8)Eu_(0.2))(Mg_(0.7)Mn_(0.3))Al₁₀O₁₇

Red phosphor: (La_(0.899)Eu_(0.1)Sm_(0.001))₂O₂S

Comparative Example 101

Blue phosphor: (Sr_(0.99)Eu_(0.01))₁₀(PO₄)₆Cl₂0.24B₂O₃

Green phosphor: BaMgAl₁₀O₁₇:Eu_(0.2), Mn_(0.2)

Red phosphor: LaO₂S:Eu_(0.099), Sm_(0.001)

Example 102

Blue phosphor: (Sr_(0.8)Ba_(0.19)Eu_(0.01))₅(PO₄)₃Cl

Green phosphor: (Ba_(0.8)Eu_(0.2))(Mg_(0.7)Mn_(0.3))Al₁₀O₁₇

Red phosphor: (La_(0.899)Eu_(0.1)Sm_(0.001))₂O₂S

Comparative Example 102

Blue phosphor: (Sr_(0.81)Ba_(0.19))₅(PO₄)₃Cl:Eu_(0.01)

Green phosphor: Ba Mg Al₁₀O₁₇:Eu_(0.2), Mn_(0.2)

Red phosphor: LaO₂S:Eu_(0.098), Sm_(0.001), Bi_(0.001)

Example 103

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₅(PO₄)₃Cl

Green phosphor: (Ba_(0.8)Eu_(0.2))(Mg_(0.7)Mn_(0.3))Al₁₀O₁₇

Red phosphor: (La_(0.899)Eu_(0.1)Sm_(0.001))₂O₂S

Comparative Example 103

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₁₀(PO₄)₆Cl₂0.24B₂O_(/)

Green phosphor: BaMgAl₁₀O₁₇: Eu_(0.2), Mn_(0.2)

Red phosphor: LaO₂S: Eu_(0.098), Ce_(0.001), Bi_(0.001)

Example 104

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₅(PO₄)₃Cl

Green phosphor: (Sr_(1.15)Ba_(0.7)Mg_(0.048)Mn_(0.002)Eu_(0.1))SiO₄

Red phosphor: (La_(0.899)Eu_(0.1)Sm_(0.001))₂O₂S

Comparative Example 104

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₁₀(PO₄)₆Cl₂0.24B₂O₃

Green phosphor: (Sr_(0.575)Ba_(0.35)Mg_(0.024))₂SiO₄:Mn_(0.002),Eu_(0.1)

Red phosphor: LaO₂S:Eu_(0.097), Sm_(0.001), Ce_(0.001), Bi_(0.001)

Example 105

Blue phosphor: (Sr_(0.8) Ca_(0.19)Eu_(0.01))₅(PO₄)₃Cl

Green phosphor: (Sr_(1.15)Ba_(0.7)Mg_(0.048)Mn_(0.002)Eu_(0.1))SiO₄

Red phosphor: (La_(0.898)Eu_(0.1)Sm_(0.002))₂O₂S

Comparative Example 105

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₁₀(PO₄)₆Cl₂0.24B₂O₃

Green phosphor: (Sr_(0.575)Ba_(0.35)Mg_(0.023))₂SiO₄:Mn_(0.002),Eu_(0.1), Ti_(0.002)

Red phosphor: LaO₂S:Eu_(0.096), Sm_(0.002), Ce_(0.001), Bi_(0.001)

Example 106

Blue phosphor: (Sr_(0.98)Eu_(0.02))₅(PO₄)₃Cl

Green phosphor: (Sr_(1.15)Ba_(0.7)Mg_(0.048)Mn_(0.002)Eu_(0.1))SiO₄

Red phosphor: (La_(0.898)Eu_(0.1)Sm_(0.002))₂O₂S

Comparative Example 106

Blue phosphor: (Sr_(0.98)Eu_(0.02))₁₀(PO₄)₆Cl₂0.24B₂O₃

Green phosphor: (Sr_(0.575)Ba_(0.35)Mg_(0.023))₂SiO₄:Mn_(0.002),Eu_(0.01), Pr_(0.002)

Red phosphor: LaO₂S: Eu_(0.096), Sm_(0.002), Ce_(0.001), Bi_(0.001)

Example 107

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₅(PO₄)₃Cl

Green phosphor: (Sr_(1.15) Ba_(0.7)Mg_(0.048)Mn_(0.002)Eu_(0.1))SiO₄

Red phosphor: (La_(0.898)Eu_(0.1)Sm_(0.002))₂O₂S

Comparative Example 107

Blue phosphor: (Sr_(0.8)Ca_(0.12)Mg_(0.01))₅(PO₄)₃Cl₃:Eu

Green phosphor: (Sr_(0.575)Ba_(0.35)Mg_(0.023))₂SiO₄:Mn_(0.002),Eu_(0.1)Pr_(0.002)Pb0.002

Red phosphor: LaO₂S:Eu_(0.096), Sm_(0.002), Bi_(0.002)

Example 108

Blue phosphor: (Sr_(0.98)Eu_(0.02))₅(PO₄)₃Cl

Green phosphor: LaO₂S:Eu_(0.097), Sm_(0.001) Red phosphor:(La_(0.899)Eu_(0.1)Sm_(0.001))₂O₂S

Comparative Example 108

Blue phosphor: (Sr_(0.98)Eu_(0.02))₁₀(PO₄)₆Cl₂0.24B₂O₃

Green phosphor: (Sr_(0.575)Ba_(0.35)Mg_(0.023))₂SiO₄:Mn_(0.002),Eu_(0.1)Li_(0.002)

Red phosphor: LaO₂S:Eu_(0.097), Sm_(0.001), Ce_(0.001), Bi_(0.001)

Example 109

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₅(PO₄)₃Cl

Green phosphor: (Sr_(1.13)Ba_(0.72)Mg_(0.048)Mn_(0.002)Eu_(0.1))SiO₄

Red phosphor: (La_(0.899)Eu_(0.1)Sm_(0.002))₂O₂S

Comparative Example 109

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₁₀(PO₄)₆Cl₂0.24B₂O₃

Green phosphor: (Sr_(0.575)Ba_(0.35)Mg_(0.023))₂SiO₄:Mn_(0.002),Eu_(0.1)Ce_(0.002)

Red phosphor: LaO₂S:Eu_(0.097), Sm_(0.001), Ce_(0.001), Bi_(0.001)

Example 110

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₅(PO₄)₃Cl

Green phosphor: (Sr_(0.995)Ba_(0.8)Mg_(0.1)Mn_(0.005)Eu_(0.1))SiO₄

Red phosphor: (La_(0.899)Eu_(0.1)Sm_(0.002))₂O₂S

Comparative Example 110

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₁₀(PO₄)₆Cl₂0.24B₂O₃

Green phosphor: :(Sr_(0.575)Ba_(0.35)Mg_(0.023))₂SiO₄:Mn_(0.002),Eu_(0.1)Sn_(0.002)

Red phosphor: LaO₂S:Eu_(0.099), Sm_(0.001)

Example 111

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₅(PO₄)₃Cl

Green phosphor: (Sr_(1.15)Ba_(0.7)Mg_(0.048)Mn_(0.002)Eu_(0.1))SiO₄

Red phosphor: (La_(0.098)Eu_(0.1)Sm_(0.002))₂O₂S

Comparative Example 111

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₁₀(PO₄)₆Cl₂0.24B₂O₃

Green phosphor: (Sr₀₅₇₅Ba_(0.374))₂SiO₄:Mn_(0.002), Eu_(0.1)

Red phosphor: LaO₂S:Eu_(0.097), Sm_(0.002), Bi_(0.001)

Example 112

Blue phosphor: (Sr_(0.8)Ba_(0.19)Eu_(0.01))₅(PO₄)₃Cl

Green phosphor: (Sr_(1.15)Ba_(0.7)Mg_(0.048)Mn_(0.002)Eu_(0.1))SiO₄

Red phosphor: (La_(0.898)Eu_(0.1)Sm_(0.002))₂O₂S

Comparative Example 112

Blue phosphor: (Sr_(0.81)Ca_(0.19))₁₀(PO₄)₆Cl₂ :Eu

Green phosphor: (Sr₀₅₅Ba_(0.35))SiO₄:Eu_(0.1)

Red phosphor: LaO₂S: Eu_(0.097), Sm_(0.001), Ce_(0.001), Bi_(0.001)

Example 113

Blue phosphor: (Sr_(0.99)Eu_(0.01))₅(PO₄)₃Cl

Green phosphor: (Sr_(1.15)Ba_(0.7)Mg_(0.048)Mn_(0.002)Eu_(0.1)) SiO₄

Red phosphor: (La_(0.898)Eu_(0.1)Sm_(0.002))₂O₂S

Comparative Example 113

Blue phosphor: (Sr_(0.8)Ca_(0.19))₅(PO₄)₃Cl:Eu_(0.05)

Green phosphor: (Sr₀₅₅Ba_(0.35))SiO₄:Eu_(0.1)

Red phosphor: LaO₂S:Eu_(0.1), Sm_(0.002)

Example 114

Blue phosphor: (Sr_(0.8)Ba_(0.19)Eu_(0.01))₅(PO₄)₃Cl

Green phosphor: (Sr_(1.15)Ba_(0.7)Mg_(0.048)Mn_(0.002)Eu_(0.1))SiO₄

Red phosphor: (La_(0.898)Eu_(0.1)Sm_(0.002))₂O₂S

Comparative Example 114

Blue phosphor: (Sr_(0.8)Ba_(0.19))₅(PO₄)₃Cl:Eu_(0.05)

Green phosphor: (Sr₀₅₇₅Ba_(0.35)Zn_(0.374))₂SiO₄: Mn_(0.002), Eu_(0.1)

Red phosphor: LaO₂S: Eu_(0.1), Sm_(0.002), Bi_(0.001)

Example 115

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₅(PO₄)₃Cl

Green phosphor: (Sr_(0.97)Eu_(0.03))Ga₂S₄

Red phosphor: (La_(0.898)Eu_(0.1)Sm_(0.002))₂O₂S

Comparative Example 115

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₁₀(PO₄)₆Cl₂0.24B₂O₃

Green phosphor: SrGa₂S₄:Eu_(0.03), Mn_(0.002)

Red phosphor: LaO₂S: Eu₀₀₉₇, Sm_(0.002), Bi_(0.001)

Example 116

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₅(PO₄)₃Cl

Green phosphor: (Sr_(1.15)Ba_(0.7)Mg_(0.048)Mn_(0.002)Eu_(0.1))SiO₄

Red phosphor: Ca_(0.99)Eu_(0.01)AlSiN₃

Comparative Example 116

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₁₀(PO₄)₆Cl₂0.24B₂O₃

Green phosphor: (Sr₀₅₇₅Ba_(0.35)Mg_(0.023))₂SiO₄: Mn_(0.002), Eu_(0.1),Ti_(0.002)

Red phosphor: CaAlSiN₃:Eu_(0.01)

Example 117

Blue phosphor: (Ba_(0.99)Eu_(0.01))MgAl₁₀O₁₇

Green phosphor: (Sr_(1.15)Ba_(0.7)Mg_(0.048)Mn_(0.002)Eu_(0.1))SiO₄

Red phosphor: (La_(0.898)Eu_(0.1)Sm_(0.002))₂O₂S

Comparative Example 117

Blue phosphor: (Ba, Mg) Al₁₀O₁₇:Eu_(0.01), Mn_(0.01)

Green phosphor: (Sr₀₅₇₅Ba_(0.35)Mg_(0.023))₂SiO₄:Mn_(0.002),Eu_(0.1)Ce_(0.002)

Red phosphor: LaO₂S: Eu₀₀₉₆, Sm_(0.002), Ce_(0.001), Bi_(0.001)

Example 118

Blue phosphor: (Ba_(0.97)Eu_(0.03))MgAl₁₀O₁₇

Green phosphor: (Sr_(1.15) Ba_(0.7)Mg_(0.048)Mn_(0.002)Eu_(0.1))SiO₄

Red phosphor: (La_(0.898)Eu_(0.1)Sm_(0.002))₂O₂S

Comparative Example 118

Blue phosphor: (Ba, Mg) Al₁₀O₁₇:Eu_(0.03), Mn_(0.01)

Green phosphor: (Sr₀₅₇₅Ba_(0.35 l Mg) _(0.024))₂SiO₄:Mn_(0.002),Eu_(0.1)

Red phosphor: LaO₂S: Eu₀₀₉₇, Sm_(0.002), Ce_(0.001)

Example 119

Blue phosphor: (Ba_(0.99)Eu_(0.01))MgAl₁₀O₁₇

Green phosphor: (Sr_(1.15)Ba_(0.7)Mg_(0.048)Mn_(0.002)Eu_(0.1))SiO₄

Red phosphor: (La_(0.898)Eu_(0.1)Sm_(0.002))₂O₂S

Comparative Example 119

Blue phosphor: BaMg₂Al₁₆O₂₇:Eu_(0.01)

Green phosphor: (Sr₀₅₅ Ba_(0.35))SiO₄:Eu_(0.1)

Red phosphor: LaO₂S:Eu₀₀₉₆, Sm_(0.002), Ce_(0.001)

Example 120

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₅(PO₄)₃Cl

Green phosphor: (Sr_(1.15)Ba_(0.7)Mg_(0.048)Mn_(0.002)Eu_(0.1))S10₄

Red phosphor: (La_(0.898)Eu_(0.1)Sm_(0.002))₂O₂S

Comparative Example 120

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₁₀(PO₄)₆Cl₂0.24B₂O₃

Green phosphor: (Sr₀₅₅Ba_(0.349))SiO₄:Eu_(0.1), Ce_(0.01)

Red phosphor: LaO₂S:Eu₀₀₉₇, Sm_(0.002), Bi_(0.001)

Example 121

Blue phosphor: (Sr_(2.55)Eu_(0.25))Mg_(1.25)Si₂O₈

Green phosphor: (Sr_(1.15)Ba_(0.7)Mg_(0.048)Mn_(0.002), Eu_(0.1))SiO₄

Red phosphor: Sr_(0.1)Ca_(0.89)Eu_(0.01)Al S N₃

Comparative Example 121

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₁₀(PO₄)₆Cl₂0.24B₂O₃

Green phosphor: (Sr₀₅₅Ba_(0.348))SiO₄:Eu_(0.1), Ce_(0.02)

Red phosphor: CaAlSiN₃:Eu_(0.01)

Example 122

Blue phosphor: (Ba Sr_(1.55)Eu_(0.25))Mg_(1.1)Si₂O₈

Green phosphor: (Sr_(1.15)Ba_(0.7)Mg_(0.047)Mn_(0.003), Eu_(0.1))SiO₄

Red phosphor: Sr_(0.085)Ca_(0.9)Eu_(0.015)AlSiN₃

Comparative Example 122

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₁₀(PO₄)₆Cl₂0.24B₂O₃

Green phosphor: (Sr₀₅₅Ba_(0.349))SiO₄:Eu_(0.1), Ce_(0.01)

Red phosphor: CaAlSiN₃:Eu_(0.015)

Example 123

Blue phosphor: (Ba_(0.99)Eu_(0.01))MgAl₁₀O₁₇

Green phosphor: (Sr_(1.15)Ba_(0.7)Mg_(0.048)Mn_(0.002)Eu_(0.1))SiO₄

Red phosphor: (La_(0.898)Eu_(0.1)Sm_(0.002))₂O₂S—70%

(Sr_(1.688)Ca_(0.2)Mg_(0.01)Eu_(0.1)Mn_(0.002))SiO₄—30%

Comparative Example 123

Blue phosphor: BaMg₂Al₁₆O₂₇:Eu_(0.01)

Green phosphor: (Sr₀₅₅Ba_(0.35))SiO₄:Eu_(0.1)

Red phosphor: LaO₂S: Eu₀₀₉₈, Sm_(0.002), Ce_(0.001), Bi_(0.001)

Example 124

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₅(PO₄)₃Cl

Green phosphor: (Sr_(1.15 l Ba) _(0.7)Mg_(0.048)Mn_(0.002)Eu_(0.1))SiO₄

Red phosphor: (La_(0.898)Eu_(0.1)Sm_(0.002))₂O₂S—70%

(Ba_(2.75)Sr_(0.05)Eu_(0.1)Mn_(0.1))MgSi₂O₈—30%

Comparative Example 124

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₁₀(PO₄)₆Cl₂0.24B₂O₃

Green phosphor: (Sr₀₅₅Ba_(0.349))SiO₄:Eu_(0.1), Ce_(0.01)

Red phosphor: LaO₂S:Eu₀₀₉₇, Sm_(0.002), Bi_(0.001)

Next, thus prepared respective blue (B), green (G) and red (R) phosphorsfor each of Examples and Comparative Examples were dispersed intotransparent resin liquids, and ultraviolet-hardening resin was alsoadded and mixed into the transparent resin liquids thereby to preparephosphor slurries for the respective colors.

Glass plates each having a size of A4 were prepared, and a blue phosphorslurry was screen-printed in a form of stripe having a width of about100 μm onto the glass plate. In order to increase a bonding strengthbetween the stripe and the glass plate, a hardening treatment using anultraviolet light was performed. With respect to a green phosphor slurryand a red phosphor slurry, the same printing process was applied, sothat stripes each having a width of about 100 μm were formed, thereby toobtain a phosphor screen having a phosphor layer 108 as shown in FIG. 8.Then, this phosphor screen was assembled into a laser light excitingsystem (UV light generating source) 109, thereby to prepare the displaydevices of the respective Examples and Comparative Examples.

When performances of thus prepared display devices are evaluated, it isimportant to evaluate a brightness (luminosity) and a color reproductionrange. Namely, when the light image is displayed on the display devicewith the same white chromaticity, a higher brightness is morepreferable. Further, when a broader ratio of the color reproductionrange with respect to an international standard (NTSC) indicating anideal triangular color reproduction range is obtained, it can be saidthat the display device can display more lights having variouschromaticity, and the liquid crystal display device or the like has amore excellent color reproducing property.

An extent of the color reproduction range is usually expressed as arelative value (%) obtained by calculating an area of a triangularregion specifying by connecting the reproduced B, G, R color points inthe chromaticity diagram when the area of a triangular region specifiedby NTSC is assumed to be 100%.

With respect to each of the above display devices of Examples 101-124and Comparative Examples 101-124, the brightness at a center of thephosphor screen and a ratio (%) of the color reproduction range withrespect to the NTSC (100%) were measured, and the results shown in theaccompanying Table 4 were obtained.

As is clear from the result shown in Table 4, according to therespective display devices of Examples, both the brightness and NTSCratio (color reproduction range ratio) are high, so that it is confirmedthat the display devices of Examples have excellent light emittingperformances in comparison with the conventional display devices usingconventional phosphors each having a conventional composition.

Next, an embodiment of the illumination device according to the presentinvention will be explained more concretely with reference to thefollowing Examples and Comparative Examples.

Examples 201-210 and Comparative Example 201

There were prepared the respective blue (B), green (G) and red (R)phosphors each having the following compositions for forming phosphorlayers of the illumination devices according to the respective Examplesand Comparative Example.

Example 201

Blue phosphor: (Sr_(0.99)Eu_(0.01))₅(PO₄)₃Cl

Green phosphor: (Ba_(0.8)Eu₀₂) (Mg_(0.7)Mn_(0.3))Al₁₀O₁₇

Red phosphor: (La_(0.899)Eu_(0.1)Sm_(0.001))₂O₂S

Example 202

Blue phosphor: (Sr_(0.8)Eu_(0.01))₅(PO₄)₃Cl

Green phosphor: (Ba_(0.8)Eu₀₂) (Mg_(0.7)Mn_(0.3))Al₁₀O₁₇

Red phosphor: (La_(0.899)Eu_(0.1)Sm_(0.001))₂O₂S

Example 203

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₅(PO₄)₃Cl

Green phosphor: (Ba_(0.8)Eu₀₂) (Mg_(0.7)Mn_(0.3))Al₁₀O₁₇

Red phosphor: (La_(0.899)Eu_(0.1)Sm_(0.001))₂O₂S

Example 204

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₅(PO₄)₃Cl

Green phosphor: (Sr_(1.15)Ba_(0.7)Mg_(0.048)Mn_(0.002)Eu_(0.1))SiO₄

Red phosphor: (La_(0.899)Eu_(0.1)Sm_(0.001))₂O₂S

Example 205

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₅(PO₄)₃Cl

Green phosphor: (Sr_(1.15)Ba_(0.7)Mg_(0.048)Mn_(0.002)Eu_(0.1))SiO₄

Red phosphor: (La_(0.898)Eu_(0.1)Sm_(0.002))₂O₂S

Example 206

Blue phosphor: (Sr_(0.98)Eu_(0.02))₅(PO₄)₃Cl

Green phosphor: (Sr_(1.15)Ba_(0.7)Mg_(0.048)Mn_(0.002)Eu_(0.1))SiO₄

Red phosphor: (La_(0.898)Eu_(0.1)Sm_(0.002))₂O₂S

Example 207

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₅(PO₄)₃Cl

Green phosphor: (Sr_(1.15)Ba_(0.7)Mg_(0.048)Mn_(0.002)Eu_(0.1))SiO₄

Red phosphor: (La_(0.898)Eu_(0.1)Sm_(0.002))₂O₂S

Example 208

Blue phosphor: (Sr_(0.98)Eu_(0.02))₅(PO₄)₃Cl

Green phosphor: (Sr_(1.15)Ba_(0.7)Mg_(0.048)Mn_(0.002)Eu_(0.1))SiO₄

Red phosphor: (La_(0.899)Eu_(0.1)Sm_(0.001))₂O₂S

Red phosphor: LaO₂S:Eu_(0.097), Sm_(0.001), Ce_(0.001), Bi_(0.001)

Example 209

Blue phosphor: (Sr_(0.8)Ca_(0.19 Eu) _(0.01))₅(PO₄)₃Cl

Green phosphor: (Sr_(1.13 l Ba) _(0.72)Mg_(0.048)Mn_(0.002)Eu_(0.1))SiO₄

Red phosphor: (La_(0.898)Eu_(0.1)Sm_(0.002))₂O₂S

Example 210

Blue phosphor: (Sr_(0.8)Ca_(0.19)Eu_(0.01))₅(PO₄)₃Cl

Green phosphor: (Sr_(0.995)Ba_(0.8)Mg_(0.1)Mn_(0.005)Eu_(0.1))SiO₄

Red phosphor: (La_(0.899)Eu_(0.1)Sm_(0.001))₂O₂S

Next, thus prepared blue, green and red (B, G, R) phosphor powders weremixed at a predetermined mixing ratio so that a chromaticity (x, y) of alight emitted from the LED lamp exhibited a chromaticity (x=0.275±0.003,y=0.250±0.003) in the XYZ color system prescribed by ClE (InternationalCommission on Illumination), thereby to prepare a mixed phosphor powder.Then, the mixed phosphor powder was dispersed into the silicone resinthereby to prepare a phosphor slurry. Further, a quartz glass tubehaving an outer diameter of 10 mm and a length of 200 mm was preparedand then, the phosphor slurry was coated onto an inner surface of thequartz glass tube, followed by hardening the coated phosphor slurry,thereby to form a predetermined phosphor film as shown in FIG. 9.

Further, one end of the quartz glass tube was sealed by a metal platesubjected to silver (Ag) plating. Then, fine silica powder (averagegrain size: 10 μm) dispersed in the silicone resin was poured in thequartz glass tube. A silver (Ag)-plated plate formed with a small holeat a center thereof was prepared, and the silver-plated plate wasattached to another end of the quartz glass tube. Under this condition,the quartz glass tube was heated to a temperature of 150° C., thereby toharden the silicone resin.

Furthermore, as shown in FIG. 9, a laser diode 205 was attached to thesilver-plated plate so as to allow a laser light having a peakwavelength of 405 nm to radiate through the small hole, thereby tomanufacture cylindrical-type laser illumination devices of therespective Examples.

With respect to the illumination devices of the respective Examplesmanufactured by changing the combination of the B, G, R phosphors, theluminous efficiency and the color reproduction range (NTSC ratio) werecomparatively measured thereby to obtain the results shown inaccompanying Table 5.

In this connection, as Comparative Example 201, the luminous efficiencyand the color reproduction range (NTSC ratio) were also measured withrespect to a conventional CCFL tube (cold cathode fluorescent lamp tube)in which a laser diode was not used as an exciting light source andmercury vapor was enclosed therein. The conventional cold cathodefluorescent lamp (CCFL) was operated under the same electrical powerlevel as those of Examples.

As is clear from the result shown in Table 5, according to the laserillumination devices of the respective Examples, it was confirmed thatthere could be simultaneously realized both the luminous efficiency andthe color reproduction range (NTSC ratio) that are equal to or moreexcellent than those of the conventional CCFL tube (cold cathodefluorescent lamp tube) into which the mercury vapor was enclosed.

In addition, unlike the conventional CCFL tube, the present inventiondoes not use harmful mercury as an enclosing component into the tube, sothat the problem of polluting environment would not occur, thus beingextremely useful for the practical use.

TABLE 1 Thickness of Phosphor Layer Transparent Blue Phosphor PowderGreen Phosphor Powder Yellow Phosphor Resin Layer Average Grain AverageGrain Powder Sample No. Substrate (mm) Composition Size (μm) CompositionSize (μm) Composition Example 1 AlN 0.2 (Sr_(0.894)Ba_(0.1) 10(Ba_(0.32)Sr_(0.19)Ca_(0.01) 11 None Eu_(0.006))₁₀Eu_(0.48))(Mg_(0.89)Mn_(0.11)) (PO₄)₆•Cl₂ Al₁₀O₁₇ Reference — — — — — —— Example 1 Example 2 Glass 0.3 (Sr_(0.42)Ba_(0.48)Ca_(0.01) 12(Ba_(0.975)Sr_(0.01)Ca_(0.009) 22 ZnS: Au_(0.0002) EpoxyEu_(0.09))₁₀(PO₄)₆•Cl₂ Eu_(0.006))(Mg_(0.51)Mn_(0.49)) Al_(0.0002)Al₁₀O₁₇ Example 3 Resin 0.4 (Sr_(0.85)Ba_(0.01)Ca_(0.09) 20(Ba_(0.799)Sr_(0.1)Ca_(0.001) 25 None Package Eu_(0.05))₁₀(PO₄)₆•Cl₂Eu_(0.1))(Mg_(0.7)Mn_(0.3)) Al₁₀O₁₇ Example 4 Alumina 0.2(Sr_(0.44)Ba_(0.49)Ca_(0.02) 40 None — (Sr_(1.58)Ba_(0.11)Mg_(0.2)Eu_(0.05))₁₀(PO₄)₆Cl₂ Eu_(0.1)Mn_(0.01))SiO₄ Comparative Resin 0.2(Sr_(0.85)Ba_(0.01)Ca_(0.09) 20 (Ba_(0.799)Sr_(0.1)Ca_(0.001) 25 NoneExample 1 Package Eu_(0.05))₁₀(PO₄)₆•Cl₂ Eu_(0.1))(Mg_(0.7)Mn_(0.3))Al₁₀O₁₇ Comparative Glass None (Sr_(0.85)Ba_(0.01)Ca_(0.09) 20(Ba_(0.799)Sr_(0.1)Ca_(0.001) 25 None Example 2 EpoxyEu_(0.05))₁₀(PO₄)₆•Cl₂ Eu_(0.1))(Mg_(0.7)Mn_(0.3)) Al₁₀O₁₇ Example 5Resin 0.2 (Sr_(0.85)Ba_(0.01)Ca_(0.09) 20 (Ba_(0.799)Sr_(0.1)Ca_(0.001)25 None Package Eu_(0.05))₁₀(PO₄)₆•Cl₂ Eu_(0.1))(Mg_(0.7)Mn_(0.3))Al₁₀O₁₇ Comparative Glass 0.3 (Sr_(0.42)Ba_(0.48)Ca_(0.01) 8(Ba_(0.975)Sr_(0.01)Ca_(0.009) 8 None Example 3 EpoxyEu_(0.09))₁₀(PO₄)₆•Cl₂ Eu_(0.006))(Mg_(0.7)Mn_(0.3)) Al₁₀O₁₇ PhosphorLayer Yellow Phosphor Total Phosphor Powder Red Phosphor Powder Contentin Thickness of Thickness of Average Grain Average Grain Phosphor LayerPhosphor Layer UV Absorbing Size (μm) Composition Size (μm) (wt %) (mm)Layer (μm) Notes Sample No. — (La_(0.98)Eu_(0.02))₂O₂S 10 80 0.1 NoneExample 1 — — — — — — CCFL Reference 22 (Sr_(0.39)Ca_(0.61))SiA 18 800.2 None Example 1 IN₃: Eu Example 2 — (Sr_(0.01)Ca_(0.99))SiA 25 40 0.2None IN₃: Eu Example 3 30 (La_(0.859)Eu_(0.14) 40 70 0.7 NoneGa_(0.001))₂O₂S Example 4 — (Sr_(0.01)Ca_(0.99))SiA 25 40 0.09 None IN₃:Eu Comparative — (Sr_(0.01)Ca_(0.99))SiA 25 40 0.2 None Example 1 IN₃:Eu Comparative — (Sr_(0.01)Ca_(0.99))SiA 25 40 0.09 50 Example 2 IN₃: EuExample 5 — (La_(0.86)Eu_(0.14))₂O₂S 7 80 02 None Comparative Example 3

TABLE 2 Energy of Peak Peak Peak Color Light having Intensity IntensityIntensity (Chroma- Wavelength of of Primary of Blue Ratio of tisity) of360-410 nm Light at Light at Primary Light Luminous Outgoing per TotalCurrent of Current of Light to Blue Thermal Flux Efficiency Light LightFlux 30 mA a 30 mA b Light a/b Resistance Transmission Sample No. lmlm/W x y mW/lm mW/nm mW/nm — ° C./W Factor % Notes Example 1 2 20 0.280.23 0.3 0.032 0.10 0.32 7 97 Reference — — — — — — — — — 90 CCFLExample 1 Example 2 4 40 0.28 0.23 0.01 0.0026 0.08 0.0325 40 99 Example3 3 30 0.28 0.23 0.4 0.1 0.20 0.5 4 90 Example 4 32 45 0.28 0.23 0.010.021 0.70 0.03 40 99 Comparative 3.2 32 0.28 0.23 0.45 0.106 0.20 0.534 87 Example 1 Comparative 1.8 18 0.28 0.23 0.41 0.1 0.20 0.5 40 85Example 2 Example 5 3.1 31 0.29 0.23 0.25 0.061 0.19 0.32 4 95Comparative 1 10 0.28 0.23 0.42 0.032 0.07 0.46 40 85 Example 3

TABLE 3 Braun Liquid Crystal Plasma Tube Display Display Item TelevisionTelevision Television Brightness ◯ ◯ ◯ Color Reproducing Property ◯ ◯ ◯Movie Display ◯ Δ ◯ Display of Black Color ◯ Δ ◯ Life ◯ ◯ ΔEnergy-Saving Performance Δ ◯ Δ Depth (Thinness) Δ ◯ ◯ ScreenEnlargement ◯ Δ ◯ Light Weight Δ ◯ ◯

TABLE 4 Brightness NTSC Ratio Sample No. (Cd/m²) (%) Example 101 210 90Example 102 220 92 Example 103 200 93 Example 104 240 75 Example 105 25076 Example 106 230 75 Example 107 220 74 Example 108 230 74 Example 109240 75 Example 110 240 75 Example 111 250 73 Example 112 240 74 Example113 250 74 Example 114 240 74 Example 115 220 80 example 116 220 75Example 117 230 74 Example 118 240 75 Example 119 240 76 Example 120 25077 Example 121 240 76 Example 122 230 75 Comparative 170 76 Example 101Comparative 150 78 Example 102 Comparative 140 80 Example 103Comparative 190 72 Example 104 Comparative 190 73 Example 105Comparative 180 72 Example 106 Comparative 170 70 Example 107Comparative 190 73 Example 108 Comparative 180 72 Example 109Comparative 180 71 Example 110 Comparative 200 72 Example 111Comparative 190 70 Example 112 Comparative 200 71 Example 113Comparative 190 72 Example 114 Comparative 180 76 Example 115Comparative 180 73 Example 116 Comparative 180 71 Example 117Comparative 180 70 Example 118 Comparative 170 72 Example 119Comparative 180 72 Example 120 Comparative  17 73 Example 121Comparative 180 72 Example 122

TABLE 5 Luminous Color Reproduction Efficiency Range Sample No. (Im/W)(NTSC Ratio) (%) Example 201 52 90 Example 202 51 92 Example 203 50 93Example 204 60 75 Example 205 62 76 Example 206 59 75 Example 207 58 74Example 208 60 74 Example 209 62 75 Example 210 57 75 Example 211 58 78Comparative Example 201 (CCFL) 50 70

1. A white LED lamp comprising: a conductive portion; a light emittingdiode chip, which is mounted on the conductive portion, for emitting aprimary light having a peak wavelength of 360 nm to 420 nm; atransparent resin layer, which is composed of a first hardenedtransparent resin, for sealing the light emitting diode chip; and aphosphor layer for covering the transparent resin layer, the phosphorlayer being formed by dispersing a phosphor powder into a secondhardened transparent resin, and the phosphor powder receiving theprimary light and radiating a secondary light having a wavelength longerthan that of the primary light, wherein an energy of the primary lightcontained in the radiated secondary light is 0.4 mW/lm or less.
 2. Thewhite LED lamp according to claim 1, wherein said phosphor powdercontains a blue phosphor powder for emitting a blue light having a peakwavelength of 430 nm to 460 nm, and a ratio of a peak strength of theprimary light with respect to that of the blue light in an emissionspectrum of the radiated secondary light is 0.5 or less.
 3. The whiteLED lamp according to claim 1, wherein said phosphor powder has anaverage grain size of 10 μm or more.
 4. The white LED lamp according toclaim 1, wherein said phosphor layer has a thickness of 0.1 mm or more.5. The white LED lamp according to claim 1, wherein said white LED lamphas a luminous efficiency of 20 lm/W or more.
 6. The white LED lampaccording to claim 1, wherein said phosphor powder contains: a bluephosphor powder for emitting blue light; a green phosphor powder foremitting green light; and a red phosphor powder for emitting red light.7. The white LED lamp according to claim 1, wherein said phosphor powdercontains: a blue phosphor powder for emitting blue light; a yellowphosphor powder for emitting yellow light; and a red phosphor powder foremitting red light.
 8. The white LED lamp according to claim 1, whereinsaid phosphor powder contains: a blue phosphor powder for emitting bluelight; a green phosphor powder for emitting green light; a yellowphosphor powder for emitting yellow light and a red phosphor powder foremitting red light.
 9. The white LED lamp according to claim 6, whereinsaid blue phosphor powder contains a blue phosphor powder having acomposition expressed by an equation (1):(Sr_(1-x-y-z)Ba_(x)Ca_(y)Eu_(z))₅(PO₄)₃Cl   (1) wherein x, y and zrespectively satisfy the relations 0≦x<0.5, 023 y<0.1, 0.005<z<0.1. 10.The white LED lamp according to claim 6, wherein said green phosphorpowder is composed of europium- manganese activated aluminate having acomposition expressed by an equation (2):(Br_(1-x-y-z)Sr_(x)Ca_(y)Eu_(z)) (Mg_(1-u)Mn_(u)) Al₁₀O₁₇   (2) whereinx, y, z and u respectively satisfy the relations 0≦x<0.2, 0≦y<0.1,0.005<z<0.5, 0.1<u<0.5.
 11. The white LED lamp according to claim 7,wherein said yellow phosphor powder contains a yellow phosphor powderhaving a composition expressed by an equation (3):ZnS: Au_(c)Al_(d)   (3) wherein c and d respectively satisfy therelations 0.0001<c, d<0.002.
 12. The white LED lamp according to claim7, wherein said yellow phosphor powder contains a yellow phosphor powderhaving a composition expressed by an equation (4):(Sr_(2-x-y-z-u)Ba_(x)Mg_(y)Eu Mn_(u)) SiO₄   (4) wherein x, y, z and urespectively satisfy the relations 0.1<x<0.4, 0.005<y<0.21, 0.05<z<0.3,0.001<u<0.04.
 13. The white LED lamp according to claim 6, wherein saidred phosphor powder is composed of europium activated lanthanumoxysulfide having a composition expressed by an equation (5):(La_(1-x-y)Eu_(x)M_(y))₂O₂S   (5) wherein M is at least one elementselected from a group consisting of Sb, Sm, Ga and Sn, while x and yrespectively satisfy the relations 0.01<x<0.15, 0≦y<0.03.
 14. The whiteLED lamp according to claim 6, wherein said red phosphor powder containsa red phosphor powder having a composition expressed by an equation (6):(Sr_(x)Ca_(1-x))SiAlN₃:Eu   (6) wherein x satisfies a relation 0≦x<0.4.15. The white LED lamp according to claim 6, wherein said phosphorpowder contains: the blue phosphor powder composed of an europiumactivated halo phosphate having the composition expressed by theequation (1); the green phosphor powder composed of aneuropium/manganese activated aluminate having the composition expressedby the equation (2); and the red phosphor powder composed of an europiumactivated lanthanum oxysulfide having the composition expressed by theequation (5).
 16. The white LED lamp according to claim 7, wherein saidblue phosphor powder contains the blue phosphor powder having thecomposition expressed by the equation (1); said yellow phosphor powdercontains at lest one of the yellow phosphor powder having thecomposition expressed by the equation (3) and the yellow phosphor powderhaving the composition expressed by the equation (4); and said redphosphor powder contains at lest one of the red phosphor powder havingthe composition expressed by the equation (5) and the red phosphorpowder having the composition expressed by the equation (6).
 17. Thewhite LED lamp according to claim 1, wherein said conductive portion isprovided on an insulating portion thereby to constitute a substrate, andthe insulating portion is either one of an alumina plate, an aluminumnitride plate and a glass epoxy plate provided with a heat radiationvia.
 18. The white LED lamp according to claim 17, wherein a thermalresistance Rth per one light emitting diode chip between a junctionportion of the light emitting diode chip and a rear surface of thesubstrate is 40° C./W or less.
 19. The white LED lamp according to claim1, wherein said conductive portion is a light reflecting electrode. 20.The white LED lamp according to claim 19, wherein said light reflectingelectrode is an electrode composed of at least one metal selected from agroup consisting of Ag, Pt, Ru, Pd and Al.
 21. The white LED lampaccording to claim 1, wherein at a surface of said conductive portion isprovided with a light reflecting layer.
 22. The white LED lamp accordingto claim 21, wherein said light reflecting layer is a cover layercontaining fine powder composed of inorganic substance selected from agroup consisting of titanium oxide, barium sulphide, alumina and silica.23. The white LED lamp according to claim 21, wherein said lightreflecting layer is a cover layer composed of at least one metalselected from a group consisting of Al, Ag, Pt, Ru and Pd.
 24. The whiteLED lamp according to claim 1, wherein at surface of said phosphor layeris further formed with a UV light absorbing layer which is formed bydispersing UV light absorbing powder into a third hardened transparentresin.
 25. The white LED lamp according to claim 24, wherein said UVlight absorbing powder is fine powder composed of inorganic substanceselected from a group consisting of titanium oxide, zinc oxide andcerium oxide.
 26. The white LED lamp according to claim 1, wherein saidlight emitting diode chip is InGaN type, GaN type or A1GaN type lightemitting diode chip.
 27. A backlight comprising the white LED lampaccording to claim
 1. 28. A lighting device comprising the white LEDlamp according to claim
 1. 29. A light emitting device comprising: alaser diode for emitting a laser light having a peak wave length of 360nm to 420 nm; and a phosphor layer for being excited by the laser lightand emitting blue, green and red lights.
 30. A display devicecomprising: a laser diode for emitting a laser light having a peak wavelength of 360 nm to 420 nm; and a phosphor screen having a predeterminedpattern which is formed by arranging phosphor layers in two dimensionaldirections, the phosphor layers emitting red, green or blue lights whenexcited by the laser light, wherein the laser light scans on thephosphor screen and an image is displayed by a light excited by thelaser light.
 31. An illumination device comprising: a laser diode foremitting a laser light having a peak wave length of 360 nm to 420 nm;and a phosphor film which is formed by mixing a phosphor for emittingblue light, a phosphor for emitting green light and a phosphor foremitting red light when the phosphors are excited by the laser light,wherein a visible light is obtained by radiating the laser light to thephosphor film.
 32. The light emitting device according to claim 29,wherein said phosphor constituting the phosphor layer for emitting theblue light has at least one composition expressed by general formulas:(Sr_(1-x-y-z)Ba_(x)Ca_(y)Eu_(z))₅(PO₄)₃Cl wherein x, y and zrespectively satisfy the relations x, y<0.3 and 0.001<z<0.2;(Ba_(1-x), Eu_(x))MgAl₁₀O₁₇ wherein x satisfies the relation 0.01<x<0.3;and(Ba_(3-x-y), Sr_(x), Eu_(y))Mg_(z)Si₂O₈ wherein x, y and z respectivelysatisfy the relations 0≦x<2.9, 0.02<y<0.4, 0.95<z<1.4.
 33. The lightemitting device according to claim 29, wherein said phosphorconstituting the phosphor layer for emitting the green light has atleast one composition expressed by general formulas:(Ba_(1-x), Eu_(x)) (Mg_(1-y), Mn_(y))Al₁₀O₁₇ wherein x and yrespectively satisfy the relations 0.05<x<0.5; and 0.1<y<0.6;(Sr_(2-y-z-ω), Ba_(x)Mg_(y)Mn_(z), Eu_(ω))SiO₄ wherein x, y, z and wrespectively satisfy the relations 0.05<x<1, 0.05<y<0.2, 0.002<z<0.009,0.03<ω<0.3;ZnS:Au_(x), Al_(y) wherein x and y respectively satisfy the relations0.0002≦x≦0.015, 0.0001≦y≦0.0012;(Sr_(1-x-y), Ca_(x), Eu_(y))Ga₂S₄ wherein x and y respectively satisfythe relations x<0.2, 0.05<y<0.3; and(Sr_(3-x), Eu_(x))Si_(y)Al_(z)O_(v)N_(ω) wherein x, y, z, v andwrespectively satisfy the relations x<0.2, 12 <y<14, 2 <z<4, 1<v<3,20<ω<22.
 34. The light emitting device according to claim 29, whereinsaid phosphor constituting the phosphor layer for emitting the red lighthas at least one composition expressed by general formulas:(La_(1-x), Eu_(x)Sm_(y))₂O₂S wherein x and y respectively satisfy therelations 0.01<x<0.2 and 0.00005<y<0.05;(Ca_(1-x), Eu_(x))AlSiN₃ wherein x satisfies the relation 0.005<x<0.03;(Sr_(2-x-y-z-u), Ca_(x)Mg_(y)Eu_(z), Mn_(u))SiO₄ wherein x, y, z and urespectively satisfy the relations 0.05<x<0.4, 0.005 <y<0.21,0.05<z<0.3, 0.001<u<0.04; and(Ba_(3-x-y-z), Sr_(x)Eu_(y)Mn_(z))Mg_(ω)Si₂O₈ wherein x, y, z andwrespectively satisfy the relations 0≦x<0.2, 0.02 <y <0.6, 0.05<z<1.5,0.95<ω<1.4.
 35. The display device according to claim 30, wherein saidphosphor constituting the phosphor layer for emitting the blue light hasat least one composition expressed by general formulas:(Sr_(1-x-y-z)Ba_(x)Ca_(y)Eu_(z))₅(PO₄)₃Cl wherein x, y and zrespectively satisfy the relations x, y <0.3 and 0.001<z<0.2;(Ba_(1-x), Eu_(x))MgAl₁₀O₁₇ wherein x satisfies the relation 0.01<x<0.3;and(Ba_(3-x-y), Sr_(x), Eu_(y))Mg_(z)Si₂O₈ wherein x, y and z respectivelysatisfy the relations 0≦x<2.9, 0.02<y<0.4, 0.95<z<1.4.
 36. The displaydevice according to claim 30, wherein said phosphor constituting thephosphor layer for emitting the green light has at least one compositionexpressed by general formulas:(Ba_(1-x)Eu_(x)) (Mg_(1-y), Mn_(y))Al₁₀O₁₇ wherein x and y respectivelysatisfy the relations 0.05<x<0.5, and 0.1<y<0.6;(Sr_(2-x-y-z-ω)Ba_(x)Mg_(y), Mn_(z), Eu_(ω))SiO₄ wherein x, y, z andcorespectively satisfy the relations 0.05<x<1, 0.05 <y<0.2, 0.002<z<0.009,0.03<ω<0.3;ZnS:Au_(x)Al_(y) wherein x and y respectively satisfy the relations0.0002≦x≦0.015, 0.0001≦y≦0.0012;(Sr_(1-x-y), Ca_(x), Eu_(y))Ga₂S₄ wherein x and y respectively satisfythe relations x<0.2, 0.05 <y<0.3; and(Sr_(3-x)Eu_(x))Si_(y)Al_(z)O_(v)N_(ω) wherein x, y, z, v and 107respectively satisfy the relations x<0.2, 12 <y<14, 2 <z<4, 1<v<3,20<ω22.
 37. The display device according to claim 30, wherein saidphosphor constituting the phosphor layer for emitting the red light hasat least one composition expressed by general formulas:(La_(1-x)Eu_(x)Sm_(y))₂O₂S wherein x and y respectively satisfy therelations 0.01<x<0.2 and 0≦y≦0.2;(Ca_(1-x), Eu_(x))AlSiN₃ wherein x satisfies the relation 0.005<x<0.03;(Sr_(2-x-y-z-u), Ca_(x)Mg_(y), Eu_(z), Mn_(u))SiO₄ wherein x, y, z and urespectively satisfy the relations 0.05<x<0.4, 0.005 <y <0.21,0.05<z<0.3, 0.001<u<0.04; and(Ba_(3-x-y-z), Sr_(x)Eu_(y), Mn_(z))Mg_(ω)Si₂O₈ wherein x, y, z andwrespectively satisfy the relations 0≦x<0.2, 0.02 <y <0.6, 0.05<z<1.5,0.95<ω<1.4.
 38. The illumination device according to claim 31, whereinsaid phosphor for emitting the blue light has at least one compositionexpressed by general formulas:(Sr_(1-x-y-z)Ba_(x)Ca_(y)Eu_(z))₅(PO₄)₃Cl wherein x, y and zrespectively satisfy the relations x, y<0.3 and 0.001<z<0.2; and(Ba_(1-x), Eu_(x))MgAl₁₀O₁₇ wherein x satisfies the relation 0.01<x<0.3.39. The illumination device according to claim 31, wherein said phosphorfor emitting the green light has at least one composition expressed bygeneral formulas:(Ba_(1-x), Eu_(x)) (Mg_(1-y), Mn_(y))Al₁₀O₁₇ wherein x and yrespectively satisfy the relations 0.05<x<0.5, and 0.1<y<0.6;(Sr_(2-x-y-z-ω), Ba_(x)Mg_(y)Mn_(z), Eu_(ω))SiO₄ wherein x, y, z andcorespectively satisfy the relations 0.05<x<1, 0≦y<0.2, 0≦z<0.009,0.03<ω<0.3;ZnS:Au_(x), Al_(y) wherein x and y respectively satisfy the relations0.002≦x≦0.015, 0.0001≦y≦0.0012;(Sr_(1-x-y), Ca_(x), Eu_(y))Ga₂S₄ wherein x and y respectively satisfythe relations x<0.2, 0.05 <y<0.3; and(Sr_(3-x)Eu_(x))Si_(y)Al_(z)O_(v)N_(ω) wherein x, y, z, v andwrespectively satisfy the relations x<0.2, 12 <y <14, 2 <z<4, 1<v<3,20<ω<22.
 40. The illumination device according to claim 31, wherein saidphosphor for emitting the red light has at least one compositionexpressed by general formulas:(La_(1-x), Eu_(x)Sm_(y))₂O₂S wherein x and y respectively satisfy therelations 0.01<x<0.2 and 0≦y≦0.2; and(Ca_(1-x), Eu_(x))AlSiN₃ wherein x satisfies the relation 0.005<x<0.03.